Table 3.
PLS calibration models results for the different soils parameters using the entire NIR spectra pre-processed with Savitzky-Golay (using 15 points filter width, second polynomial order and first derivative) followed by SNV and then mean centered.
| Parameters | LV | RMSEC | RMSECV | RMSEP | R2C | R2P | RER |
|---|---|---|---|---|---|---|---|
| pH -H2O | 8 | 0.19 | 0.44 | 0.27 | 0.94 | 0.85 | 11 |
| pH - KCl | 6 | 0.30 | 0.50 | 0.25 | 0.73 | 0.78 | 7 |
| Corg | 6 | 1.50 | 2.20 | 1.70 | 0.86 | 0.84 | 9 |
| CnH | 6 | 0.79 | 1.30 | 1.50 | 0.85 | 0.27 | 4 |
| N | 6 | 0.09 | 0.14 | 0.10 | 0.91 | 0.90 | 13 |
| C/N | 3 | 3.70 | 4.50 | 2.80 | 0.42 | 0.55 | 6 |
| Ca2+ | 8 | 1.40 | 3.50 | 1.70 | 0.98 | 0.98 | 17 |
| Mg2+ | 5 | 0.42 | 0.64 | 0.52 | 0.97 | 0.97 | 19 |
| Na+ | 2 | 0.12 | 0.13 | 0.09 | 0.37 | 0.46 | 5 |
| K+ | 6 | 0.06 | 0.09 | 0.08 | 0.75 | 0.56 | 5 |
| SB | 5 | 2.20 | 4.40 | 3.00 | 0.97 | 0.95 | 16 |
| Al3+ | 6 | 0.20 | 0.34 | 0.21 | 0.55 | 0.69 | 7 |
| CEC | 5 | 0.65 | 1.00 | 0.77 | 0.94 | 0.89 | 11 |
| ECEC | 7 | 1.80 | 4.50 | 2.40 | 0.98 | 0.97 | 19 |
| GSB | 7 | 19.00 | 52.00 | 27.00 | 0.97 | 0.93 | 13 |
| GSA | 6 | 8.70 | 13.00 | 11.00 | 0.68 | 0.49 | 5 |
| P | 4 | 13.00 | 18.00 | 14.00 | 0.19 | 0.07 | 4 |
| K | 5 | 27.00 | 38.00 | 31.00 | 0.61 | 0.36 | 5 |