. 2023 Jan 20;62(50):20593–20607. doi: 10.1021/acs.inorgchem.2c04123

Table 1. Bond Lengths of the Coordination Spheres of [GaL²]⁺ Compared to [Ga(dedpa)]⁺,¹³ [Ga(dedpa-N,N′-alkyl-NI)],¹⁶ [Ga(H₂BEDpa)]⁺,¹⁹ and [Ga(dp-N-NO₂)]⁺ ¹³.

	[GaL²]⁺	[Ga(dedpa)]⁺	[Ga(dedpa-N,N′-propyl-4NI)]⁺	[Ga(dedpa-N,N′-ethyl-2NI)]⁺	[Ga(H₂BEDpa)]⁺	[Ga(dp-N-NO₂)]⁺
Ga–N1 (pyr-N)	1.9877(9)	1.9866(16)	1.985(9)	1.980(2)	1.975(15)	1.992(5)
Ga–N2 (en-N)	2.1980(9)	2.1115(16)	2.177(3)	2.2172(19)	2.147(15)	2.188(5)
Ga–N3 (en-N)	2.1600(9)	2.1132(16)	2.183(2)	2.2172(19)	2.185(15)	2.159(5)
Ga–N4 (pyr-N)	1.9932(9)	1.9902(16)	1.996(9)	1.980(2)	1.982(15)	1.981(5)
Ga–O1 (COO^–)	1.9701(8)	1.9708(13)	2.038(12)	1.9626(16)	1.982(12)	1.967(4)
Ga–O3 (COO^–)	1.9805(8)	1.9828(13)	2.068(10)	1.9626(16)	1.969(13)	1.976(4)

Table 1. Bond Lengths of the Coordination Spheres of [GaL2]+ Compared to [Ga(dedpa)]+,13 [Ga(dedpa-N,N′-alkyl-NI)],16 [Ga(H2BEDpa)]+,19 and [Ga(dp-N-NO2)]+ 13.