Table 3. Protonation Constantsa (log KHqL) of H2L1 and H2L2.
| equilibrium reaction | H2L1 | H2L2 |
|---|---|---|
| L + H+ ⇆ HL | 10.86(1) | 8.14(1) |
| HL + H+ ⇆ H2L | 9.91(1) | 4.98(1) |
| H2L + H+ ⇆ H3L | 6.78(1) | 3.22(1) |
| H3L + H+ ⇆ H4L | 4.23(1) | 2.14(4) |
| H4L + H+ ⇆ H5L | 2.79(1) | |
| H5L + H+ ⇆ H6L | 2.01(6) | |
| H6L + H+ ⇆ H7L | 0.37(2)b | |
| ∑log KHqL | 36.95 | 18.48 |
Values were obtained from UV potentiometric titrations (25 °C, l = 0.2 cm, and I = 0.16 M NaCl). KHqL defined as [HqL]/([H][Hq–1L]).
From acidic in-batch UV titrations [25 °C, l = 1 cm, I = 0.16 M NaCl (when possible)]. Charges are omitted for clarity.