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. 2023 Jan 20;62(50):20593–20607. doi: 10.1021/acs.inorgchem.2c04123

Table 3. Protonation Constantsa (log KHqL) of H2L1 and H2L2.

equilibrium reaction H2L1 H2L2
L + H+ ⇆ HL 10.86(1) 8.14(1)
HL + H+ ⇆ H2L 9.91(1) 4.98(1)
H2L + H+ ⇆ H3L 6.78(1) 3.22(1)
H3L + H+ ⇆ H4L 4.23(1) 2.14(4)
H4L + H+ ⇆ H5L 2.79(1)  
H5L + H+ ⇆ H6L 2.01(6)  
H6L + H+ ⇆ H7L 0.37(2)b  
∑log KHqL 36.95 18.48
a

Values were obtained from UV potentiometric titrations (25 °C, l = 0.2 cm, and I = 0.16 M NaCl). KHqL defined as [HqL]/([H][Hq–1L]).

b

From acidic in-batch UV titrations [25 °C, l = 1 cm, I = 0.16 M NaCl (when possible)]. Charges are omitted for clarity.