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. 2023 Sep 13;62(50):20699–20709. doi: 10.1021/acs.inorgchem.3c01983

Table 3. Binding Distances M–X (Å) of the [M(mcp)(H2O)](m−2)+ Complexes (M = Ba2+, La3+, Eu3+, Lu3+, Pb2+, and Ra2+) in Aqueous Solutionsawith Atom Assignment in the Macropa Structure Shown in Figure 8.

  (M−)X
  Pb–X Ba–X Ra–X La–X Eu–X Lu–X
O1 (mcp) 3.09 3.00 3.07 2.84 2.72 2.37
O2 (mcp) 3.29 3.01 3.12 2.92 2.75 2.89
O3 (mcp) 2.93 3.19 2.83 2.97
O4 (mcp) 3.08 3.25 2.95 2.98
N1 (mcp) 2.91 3.02 3.10 2.98 2.89 2.57
N2 (mcp) 3.19 3.22 2.98 2.97
O5 (mcp) 2.39 2.70 2.72 2.44 2.29 2.17
O6 (mcp) 2.35 2.70 2.78 2.45 2.32 2.19
N3 (mcp) 2.54 2.88 2.88 2.70 2.54 2.37
N4 (mcp) 2.71 2.85 2.94 2.70 2.57 2.66
O (H2O) 2.96 3.10 2.59 2.45 2.25
estimated total CN 8 11 11 11 10 8
a

Atom pairs with distances above 3.4 Å are considered to form no coordinative bond and are marked with “–”.