Table 3. Binding Distances M–X (Å) of the [M(mcp)(H2O)](m−2)+ Complexes (M = Ba2+, La3+, Eu3+, Lu3+, Pb2+, and Ra2+) in Aqueous Solutionsawith Atom Assignment in the Macropa Structure Shown in Figure 8.
| (M−)X |
||||||
|---|---|---|---|---|---|---|
| Pb–X | Ba–X | Ra–X | La–X | Eu–X | Lu–X | |
| O1 (mcp) | 3.09 | 3.00 | 3.07 | 2.84 | 2.72 | 2.37 |
| O2 (mcp) | 3.29 | 3.01 | 3.12 | 2.92 | 2.75 | 2.89 |
| O3 (mcp) | – | 2.93 | 3.19 | 2.83 | 2.97 | – |
| O4 (mcp) | 3.08 | 3.25 | 2.95 | 2.98 | – | – |
| N1 (mcp) | 2.91 | 3.02 | 3.10 | 2.98 | 2.89 | 2.57 |
| N2 (mcp) | – | 3.19 | 3.22 | 2.98 | 2.97 | – |
| O5 (mcp) | 2.39 | 2.70 | 2.72 | 2.44 | 2.29 | 2.17 |
| O6 (mcp) | 2.35 | 2.70 | 2.78 | 2.45 | 2.32 | 2.19 |
| N3 (mcp) | 2.54 | 2.88 | 2.88 | 2.70 | 2.54 | 2.37 |
| N4 (mcp) | 2.71 | 2.85 | 2.94 | 2.70 | 2.57 | 2.66 |
| O (H2O) | – | 2.96 | 3.10 | 2.59 | 2.45 | 2.25 |
| estimated total CN | 8 | 11 | 11 | 11 | 10 | 8 |
Atom pairs with distances above 3.4 Å are considered to form no coordinative bond and are marked with “–”.