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. 2023 Nov 27;15(1):146–153. doi: 10.1039/d3sc04955h

Enthalpy and entropy changes in the association of the corresponding numbers of EtOH molecules bonding with the CA˙ radical (i) or CA2− anion (j).

Number of EtOH ΔHas (kJ mol−1) ΔSas (J K−1 mol−1)
CA˙ i = 1 −9.1 ± 0.2 −39 ± 1
i = 2 −12 ± 0 −66 ± 0
CA2− j = 2 −34 ± 1 −59 ± 3
j = 4 −77 ± 0 −180 ± 1