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. 2023 Nov 30;56(24):3640–3653. doi: 10.1021/acs.accounts.3c00588

Table 1. Comparison of the Redox Activity and Redox Potentials of (N,N-Bidentate)Ni(Aryl) Complexes.

Ni complexes redox activity E1/2 [Ni(II)/(I)] (V vs Fc+/Fc)
(phen)Ni(Mes)Br61 yes –1.50
(bpy)Ni(Mes)Br62 yes –1.79
(tBupyrox)Ni(Dipp)Br56 yes –1.35
(dMebiox)Ni(Dipp)Br 4558 no –2.12