Table 3. Anion Association Constants for Receptors 1 and 2 (K1:1A, M–1, Anion Binding Mode A) and 16 (K1:1, M–1) in the Presence of 1 equiv of K+.
|
1 |
2 |
16 |
||||||
|---|---|---|---|---|---|---|---|---|
| anion | K1:1A a | αb | Ac (%) | K1:1A a | αb | Ac (%) | K1:1A a | αb |
| Cl– | 9500 ± 200 | 2.6 | 63 | 5300 ± 200 | 2.2 | 57 | 34200 ± 600 | 12.7 |
| Br– | 21200 ± 1300 | 4.1 | 83 | 6100 ± 200 | 2.1 | 73 | 54000 ± 4600 | 13.5 |
| I– | 34200 ± 2700 | 7.4 | >95 | 17800 ± 600 | 5.2 | >90 | 43100 ± 3700 | 13.5 |
Solvent: 3:1 CDCl3:CD3CN at 298 K. Values reported as the mean and the standard error of the mean from independently repeated experiments.
Binding enhancement factors in the presence of K+.
Contributions of anion binding mode A to overall 1:1 binding.