Skip to main content
. 2023 Dec 7;145(50):27367–27379. doi: 10.1021/jacs.3c07774

Table 3. Anion Association Constants for Receptors 1 and 2 (K1:1A, M–1, Anion Binding Mode A) and 16 (K1:1, M–1) in the Presence of 1 equiv of K+.

  1
2
16
anion K1:1Aa αb Ac (%) K1:1Aa αb Ac (%) K1:1Aa αb
Cl 9500 ± 200 2.6 63 5300 ± 200 2.2 57 34200 ± 600 12.7
Br 21200 ± 1300 4.1 83 6100 ± 200 2.1 73 54000 ± 4600 13.5
I 34200 ± 2700 7.4 >95 17800 ± 600 5.2 >90 43100 ± 3700 13.5
a

Solvent: 3:1 CDCl3:CD3CN at 298 K. Values reported as the mean and the standard error of the mean from independently repeated experiments.

b

Binding enhancement factors in the presence of K+.

c

Contributions of anion binding mode A to overall 1:1 binding.