Table 5. Vaporization Enthalpies for 7M4MC.
temperature T/K | mass m/mg | (dm/dt)·109 kg/s | ν·103 (kg K mol)1/2 m–2 s–1 | ln ν | 103/T K |
---|---|---|---|---|---|
438.15 | 1.174 | 3.630 | 80.483 | –2.520 | 2.282 |
443.15 | 1.164 | 4.550 | 101.455 | –2.288 | 2.257 |
448.15 | 1.149 | 5.700 | 127.813 | –2.057 | 2.231 |
453.15 | 1.115 | 7.040 | 158.738 | –1.840 | 2.207 |
458.15 | 1.109 | 8.640 | 195.887 | –1.630 | 2.183 |
463.15 | 1.003 | 10.590 | 241.404 | –1.421 | 2.159 |
468.15 | 0.999 | 12.800 | 293.353 | –1.226 | 2.136 |
473.15 | 0.988 | 15.350 | 353.668 | –1.039 | 2.113 |
478.15 | 0.973 | 18.300 | 423.858 | –0.858 | 2.091 |
483.15 | 0.855 | 21.680 | 504.763 | –0.684 | 2.070 |
488.15 | 0.723 | 25.320 | 592.554 | –0.523 | 2.049 |
series I | |||
ln ν = 17.06–8570.44/T | r2 = 0.9994 | σm = 71.09, σy = 0.15 | ΔlgHm (463.15 K)/kJ mol–1 = (71.3 ± 0.6)a |
series II | |||
ln ν = 16.85–8461.06/T | r2 = 0.999 | σm = 120.77, σy = 0.26 | ΔlgHm (463.15 K)/kJ mol–1 = (70.3 ± 1.0)a |
series III | |||
ln ν = 16.96–8526.61/T | r2 = 0.9992 | σm = 110.89, σy = 0.24 | ΔlgHm (463.15 K)/kJ mol–1 = (70.9 ± 0.9)a |
series IV | |||
ln ν = 16.77–8455.23/T | r2 = 0.9997 | σm = 118.56, σy = 0.26 | ΔlgHm (463.15 K)/kJ mol–1 = (70.3 ± 1.0)a |
weighted average: ⟨ΔlgHm (463.15 K) = (70.9 ± 0.8) kJ mol–1⟩ |
The uncertainty corresponds to the combined standard and includes the uncertainties of the slope, the rate of mass loss, and the temperature.