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. 2023 Dec 14;8(51):49037–49045. doi: 10.1021/acsomega.3c06756

Table 5. Vaporization Enthalpies for 7M4MC.

temperature T/K mass m/mg (dm/dt)·109 kg/s ν·103 (kg K mol)1/2 m–2 s–1 ln ν 103/T K
438.15 1.174 3.630 80.483 –2.520 2.282
443.15 1.164 4.550 101.455 –2.288 2.257
448.15 1.149 5.700 127.813 –2.057 2.231
453.15 1.115 7.040 158.738 –1.840 2.207
458.15 1.109 8.640 195.887 –1.630 2.183
463.15 1.003 10.590 241.404 –1.421 2.159
468.15 0.999 12.800 293.353 –1.226 2.136
473.15 0.988 15.350 353.668 –1.039 2.113
478.15 0.973 18.300 423.858 –0.858 2.091
483.15 0.855 21.680 504.763 –0.684 2.070
488.15 0.723 25.320 592.554 –0.523 2.049
series I
ln ν = 17.06–8570.44/T r2 = 0.9994 σm = 71.09, σy = 0.15 ΔlgHm (463.15 K)/kJ mol–1 = (71.3 ± 0.6)a
series II
ln ν = 16.85–8461.06/T r2 = 0.999 σm = 120.77, σy = 0.26 ΔlgHm (463.15 K)/kJ mol–1 = (70.3 ± 1.0)a
series III
ln ν = 16.96–8526.61/T r2 = 0.9992 σm = 110.89, σy = 0.24 ΔlgHm (463.15 K)/kJ mol–1 = (70.9 ± 0.9)a
series IV
ln ν = 16.77–8455.23/T r2 = 0.9997 σm = 118.56, σy = 0.26 ΔlgHm (463.15 K)/kJ mol–1 = (70.3 ± 1.0)a
weighted average: ⟨ΔlgHm (463.15 K) = (70.9 ± 0.8) kJ mol–1
a

The uncertainty corresponds to the combined standard and includes the uncertainties of the slope, the rate of mass loss, and the temperature.