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. 2023 Dec 13;8(51):49259–49269. doi: 10.1021/acsomega.3c07644

Table 2. Comparison of the Osmotic Pressures of Draw Agents from the Literature.

draw agent concentration osmotic pressure ref.
P4444 DMBSa 70 wt % 25 barb (11)
P4444 TFAc 70 wt % 38 barb (11)
polyethylene glycold 40 wt % 50 bare (46)
PAGBf 40 wt % 20 bare (46)
ethylene oxide-propylene oxide copolymerg 70 wt % 96 bare (47)
PAANah 0.12 g/mL 8.1 bari (48)
PSSS-PNIPAMj 33.3 wt % 28.6 bark (49)
trimethylaminel 1.0 M 48.8 barl (50)
l-PDMAAm 50 wt % >170 barm This work
a

P4444 = tetrabutylphosphonium, DMBS = 2,4-dimethylbenzene sulfonate.

b

Measured by vapor pressure osmometer.

c

TFA = trifluoroacetate.

d

Mw = 4000 g/mol.

e

Measured by water activity method. The water activity aw of the DS solutions at 25 ± 1 °C was measured using a water activity meter.

f

PAGB = poly (propylene glycol-ran-ethylene glycol) monobutyl ether, Mw = 4000 g/mol.

g

Ethylene oxide-propylene oxide copolymer, Mw = 2000 g/mol.

h

PAA Na= poly(acrylic acid) sodium salts, Mw = 1800 g/mol.

i

The osmolality of draw solutions was converted to osmotic pressure using a model 3250 osmometer.

j

PSSS-PNIPAM = poly(sodium styrene-4-sulfonate-co-n-isopropylacrylamide), 15 wt % SSS.

k

Measured by direct membrane osmometer.

l

Measured by a stream analyzer, under CO2.

m

Under CO2.