TABLE 2.
Relative yields of products formed from the conversion of 4-alkylphenols by vanillyl-alcohol oxidase from P. simplicissimum
| Substrate | Relative yield (%)a
|
||
|---|---|---|---|
| 4-Hydroxy-phenyl alcohol | 4-Hydroxy-phenyl alkanone | 4-Hydroxy-phenyl alkenes | |
| 4-Ethylphenolb | 76 | <1 | 24 |
| 4-n-Propylphenolb | 68 | <1 | 32 |
| 2-Methoxy-4-n-propylphenolb | 90 | <1 | 10 |
| 4-Isopropylphenol | 20 | <1 | 80 |
| 4-sec-Butylphenol | 26 | 0 | 74 |
| 4-n-Butylphenol | 0 | 0 | 100 |
| 4-n-Pentylphenol | 0 | 0 | 100 |
| 4-n-Heptylphenol | 0 | 0 | 100 |
| 4-(3′-Methylcrotyl)phenol | 40 | 0 | 60 |
| 5-Indanol | 16 | 60 | 24 |
| 5,6,7,8-Tetrahydro-2-naphthol | 4 | 2 | 94 |
Products were identified by HPLC, GC-MS, and 1H-NMR analyses, and relative yields, calculated from HPLC and GC-MS analyses, were determined at saturating substrate concentrations.
Data from Drijfhout et al. (3).