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Oak Ridge Thermal Ellipsoid Plot (ORTEP) drawing at the 50% probability level of crystal structures: a) [Au(DippPZI)(ACD)], b) [Au(DippPZI)(Cz)], c) [Au(DippPZI)(DPA)], d) [Au(DippPZI)(DPAC)], and e) [Au(DippPZI)(DMAC)]. The d 1 and d 1′ are C─H···π distances between the H atoms in the amido ligand and the centroids of the peripheral Dipp units of the carbene ligand (red dotted lines).
