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. 2023 Dec 16;10(1):e23840. doi: 10.1016/j.heliyon.2023.e23840

Table 5.

FTIR absorption frequencies of some selected MOFs.

MOFs Organic Linker FTIR Absorption Frequency (cm−1)
Reference
Not Coordinated
-CO2H
Coordinated
-CO2 Asymmetrical Stretching
-CO2 Symmetrical Stretching
UiO-66-Zr BDC 1670 1584; 1393 [92,129]
NH2-UiO-66-Zr NH2-BDC 1656 1497,1564; 1385,1424 [94]
MIL-53-Al BDC 1730–1650 1574,1505; 1443,1397 [4]
MIL-96-Al BTC 1654 1597; 1457,1396 [4]
NH2-MIL-53 NH2-BDC 1688 1565, 1494; 1440, 1389 [4]
MOF-5-Zn BDC 1654 1608,1540; 1410,1340 [132]
HKUST-1 BTC 1700 1450,1649; 1373,1548 [114,133]
MIL-100 (Fe) BTC 1750 1690: Nil [8]
NH2-MIL-101(Fe) NH2-BDC 1659 1583; 1436 [131]
NO2-UiO-66 (Zr) BDC-NO2 1650 1590,1495; 1409,1389 [111]
2OH-UiO-66 (Zr) BDC-OH2 1659 1500; 1380 [54]
MIL-47(VIII) BDC 1695–1708 1542,1566; 1393, 1420 [134]
MIL-101(Cr) BDC 1700 Nil; 1404 [135]