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. 2023 Dec 20;16(1):27. doi: 10.3390/polym16010027

Table 4.

Chlorinated organic compounds produced in the pyrolysis process of EPET-PVC-CuO.

Product Retention Time (min) Product Content (wt.%)
440 °C 640 °C
Allyl chloride 1.840 - 0.1
1,6-Dichlorohexane 2.305 - 0.03
Chloroaromatics 1 0.06 1.23
Chlorobenzene 5.790 - 0.91
1,4-Dichlorobenzene 10.310 - 0.14
1,2-Dichlorobenzene 11.310 0.01 0.01
1,2,3-Trichlorobenzene 13.400 - 0.06
2,4,6-Trichlorobenzene 15.555 0.05 -
2-Chlorobiphenyl 16.730 - 0.11
Chloroaromatic derivatives 1 2.1 1.18
2-Chlorobenzoic acid 17.375 0.54 0.15
2,5-Dichlorobenzoic acid 18.850 0.37 0.02
1-(4-Chlorophenyl)-2-phenylethan-1,2-dione 19.400 0.20 0.13
2-Chloro-2-phenyl acetophenone 22.170 - 0.14
2-Chlorobenzoic acid-2-oxo-2-phenylethyl ester 22.525 0.96 0.62
3,4-Dichloro-benzophenone 23.665 0.03 0.12
Chloroesters 1 0.34 0.38
4-Ethylbenzoic acid-2-chloroethyl ester 17.750 0.15 -
Phthalic acid-di(2-chloroethyl) ester 19.505 - 0.38
Isophthalic acid-2-chloroethyl ethyl ester 19.570 0.19 -
Acyl chlorides 1 0.04 0.43
p-Chlorobenzoyl chloride 14.830 0.04 0.32
p-Phenylphenacyl chloride 21.910 - 0.11

1 Types of products and their corresponding total contents.