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. 2023 Dec 29;29(1):201. doi: 10.3390/molecules29010201

Table 3.

Yields (%) of photoproducts obtained from the starting compounds 15 under direct irradiation for reactions performed in a batch reactor (followed by HPLC).

Compound Wavelength (nm) Conversion
(%)
Yields of Photoproducts (%)
Irr. Time cis- Dimer Cycl. * Cycl.2OH ** trans- Undefined
1 313 80 30 min 52 8 3 1 20 16
365 100 30 min 91 - 7 2 - -
2 313 91 30 min 65 - 12 4 19 -
365 93 30 min 62 - 9 5 24 -
3 313 17 30 min 17 - - - 83 -
365 31 30 min 24 - 7 - 69 -
4 313 75 30 min 58 - 2 - 25 15
365 83 30 min 83 - - - 17 -
5 313 90 30 min 45 - 15 - 10 30
365 85 30 min 38 - 19 - 15 28

* product of photochemical electrocyclization depending on the starting compound (7, 11, 1315, Scheme 1, Scheme 2 and Scheme 3); ** cyclization products with 2OH functional groups (8 and 12, Scheme 1 and Scheme 2).