Table 8.
Comp. | Catalyst | Retention Time (min) | Wavelength (nm)/Temp. °C | Flow Rate (mL/min) | Conversion (%) | Productivity (μmol mL−1 min−1) |
Yields of Photoproducts (%) | ||||
---|---|---|---|---|---|---|---|---|---|---|---|
cis- | Dimer | Cycl. ** | trans- | Undefined | |||||||
1 | - | 2 | 365/22 | 0.5 | 94 | 0.470 | 94.0 | - | - | 6.0 | - |
2 | - | 2 | 365/22 | 0.5 | 61.6 | 0.308 | 61.6 | - | - | 38.4 | - |
3 | - | 2 | 365/22 | 0.5 | 91.7 | 0.458 | 71.0 | - | - | 8.3 | 20.7 |
4 | - | 2 | 365/22 | 0.5 | 92.2 | 0.461 | 81.9 | - | - | 7.8 | 10.3 |
5 | - | 2 | 365/22 | 0.5 | 91.0 | 0.455 | 22.5 | 4.8 | 29.8 | 9.0 | 30.1 |
1 | FbA | 10 | 420/22 | 0.1 | 100 | 0.500 | - | 58.1 | 19.3 | - | 22.6 |
2 | FbA | 10 | 420/22 | 0.1 | 40.2 | 0.201 | 8.1 | - | - | 59.8 | 32.1 |
3 | FbA | 10 | 420/22 | 0.1 | 100 | 0.500 | - | 6.4 | 93.6 | - | - |
4 | FbA | 10 | 420/22 | 0.1 | 100 | 0.500 | - | 58.0 | 13.8 | - | 28.1 |
5 | FbA | 10 | 420/22 | 0.1 | 100 | 0.500 | - | - | 90.1 | - | 9.9 |
HPLC analyses values read at 320 nm; ** product of photochemical electrocyclization reaction.