Table 3.
The isotherm constants for the adsorption of Eu(III) ions onto Phy/B mixtures
| Phy/B | Phy/B | |||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| 100/0 | 75/25 | 50/50 | 25/75 | 0/100 | 100/0 | 75/25 | 50/50 | 25/75 | 0/100 | |
| pH 4.5, L:S 100:1 | pH 7.0, L:S 100:1 | |||||||||
| Freundlich isotherm | ||||||||||
| 1/n | 0.2127 | 0.2306 | 0.2431 | 0.2705 | 0.3133 | 0.2282 | 0.2476 | 0.2571 | 0.2885 | 0.4141 |
| KF | 1.341 | 2.389 | 4.374 | 7.994 | 17.97 | 2.541 | 5.813 | 10.61 | 15.07 | 17.34 |
| R2 | 0.9711 | 0.9737 | 0.9877 | 0.9654 | 0.9076 | 0.9848 | 0.9161 | 0.9612 | 0.9608 | 0.9891 |
| SSE | 0.37 | 1.86 | 2.03 | 6.03 | 19.61 | 1.38 | 20.44 | 12.30 | 10.49 | 7.35 |
| χ2 | 0.29 | 1.60 | 1.78 | 3.95 | 7.72 | 1.85 | 7.58 | 3.07 | 7.01 | 3.41 |
| Langmuir isotherm | ||||||||||
| q | 3.50 | 6.60 | 13.62 | 16.42 | 19.16 | 7.20 | 12.14 | 19.33 | 20.37 | 20.56 |
| qL | 3.512 | 6.649 | 13.68 | 16.48 | 19.80 | 7.24 | 12.41 | 19.38 | 20.46 | 21.22 |
| KL | 0.2537 | 0.3684 | 0.5203 | 9.661 | 27.38 | 2.821 | 3.658 | 3.784 | 6.315 | 7.291 |
| R2 | 0.9499 | 0.9635 | 0.9373 | 0.9474 | 0.9884 | 0.9297 | 0.9747 | 0.9674 | 0.9607 | 0.9729 |
| SSE | 0.77 | 1.10 | 1.43 | 1.49 | 1.95 | 6.44 | 2.49 | 6.26 | 10.56 | 8.35 |
| χ2 | 2.71 | 0.75 | 7.96 | 1.27 | 0.64 | 2.79 | 2.14 | 2.94 | 3.42 | 5.10 |
| Dubinin-Raduskevich isotherm | ||||||||||
| qD | 0.0400 | 0.0810 | 0.1580 | 0.2010 | 0.5660 | 0.0810 | 0.1331 | 0.3210 | 0.4650 | 0.9980 |
| β·10−3 | 1.677 | 1.849 | 1.923 | 1.409 | 1.796 | 1.724 | 1.299 | 1.672 | 1.74 | 1.807 |
| E | 17.26 | 16.44 | 16.12 | 18.84 | 16.68 | 17.03 | 19.62 | 17.29 | 16.95 | 16.63 |
| R2 | 0.9890 | 0.9929 | 0.9767 | 0.9838 | 0.9276 | 0.9932 | 0.9633 | 0.9856 | 0.9806 | 0.9909 |
| SSE | 0.22 | 0.51 | 2.21 | 3.19 | 2.87 | 0.61 | 2.33 | 4.90 | 5.17 | 3.15 |
| χ2 | 0.40 | 0.46 | 0.98 | 2.35 | 3.73 | 1.03 | 2.38 | 2.88 | 2.32 | 2.31 |
| Sips isotherm | ||||||||||
| qS | 4.892 | 8.883 | 16.67 | 20.09 | 31.12 | 12.67 | 12.67 | 23.69 | 27.23 | 59.39 |
| KS | 0.4069 | 0.3816 | 0.5053 | 0.9750 | 1.451 | 0.2721 | 1.007 | 1.168 | 1.563 | 0.4178 |
| mS | 0.3869 | 0.4318 | 0.3909 | 0.5867 | 0.3614 | 0.3293 | 0.5262 | 0.5037 | 0.5187 | 0.4996 |
| R2 | 0.9909 | 0.9961 | 0.9935 | 0.9853 | 0.9697 | 0.9919 | 0.9946 | 0.9962 | 0.9893 | 0.9902 |
| SSE | 0.19 | 0.27 | 0.82 | 1.56 | 8.30 | 0.73 | 0.77 | 1.83 | 5.60 | 4.66 |
| χ2 | 0.18 | 0.28 | 0.92 | 1.59 | 4.32 | 1.19 | 1.13 | 2.30 | 2.91 | 2.66 |
| pH 4.5, L:S 500:1 | pH 7.0, L:S 500:1 | |||||||||
| Freundlich isotherm | ||||||||||
| 1/n | 0.1964 | 0.2567 | 0.3281 | 0.1991 | 0.1316 | 0.1994 | 0.2059 | 0.2274 | 0.2114 | 0.2183 |
| KF | 0.4725 | 5.3825 | 8.977 | 15.37 | 25.47 | 0.5155 | 9.671 | 14.776 | 21.07 | 26.13 |
| R2 | 0.9299 | 0.9807 | 0.9807 | 0.9664 | 0.9013 | 0.9441 | 0.9739 | 0.9659 | 0.9645 | 0.9219 |
| SSE | 0.0974 | 6.46 | 11.72 | 12.49 | 293.6 | 0.1014 | 5.38 | 7.56 | 12.24 | 156.3 |
| χ2 | 0.163 | 5.31 | 3.11 | 4.02 | 1.63 | 0.1823 | 6.15 | 5.40 | 3.65 | 1.93 |
| Langmuir isotherm | ||||||||||
| q | 7.90 | 17.9 | 27.5 | 36.8 | 44.00 | 19.5 | 26.00 | 41.80 | 52.50 | 61.0 |
| qL | 7.973 | 17.95 | 27.71 | 37.15 | 40.47 | 20.56 | 27.70 | 42.33 | 53.26 | 61.45 |
| KL | 0.084 | 0.2958 | 0.4557 | 0.537 | 21.18 | 0.1089 | 0.1060 | 0.6917 | 1.129 | 1.587 |
| R2 | 0.9366 | 0.9711 | 0.9870 | 0.9624 | 0.9815 | 0.9488 | 0.9611 | 0.9617 | 0.9629 | 0.9482 |
| SSE | 4.74 | 1.09 | 2.19 | 2.70 | 31.96 | 2.347 | 1.88 | 2.65 | 2.88 | 143.8 |
| χ2 | 0.304 | 1.64 | 2.67 | 3.71 | 1.24 | 0.0126 | 1.23 | 2.80 | 2.87 | 1.559 |
| Dubinin-Raduskevich isotherm | ||||||||||
| qD | 0.1030 | 0.237 | 0.351 | 0.391 | 0.4110 | 0.2470 | 0.258 | 0.481 | 0.586 | 0.7090 |
| β·10−3 | 1.361 | 1.934 | 1.923 | 1.408 | 1.231 | 2.11 | 1.472 | 1.76 | 1.541 | 1.562 |
| E | 14.05 | 16.07 | 16.12 | 18.44 | 20.18 | 15.31 | 18.43 | 16.83 | 18.03 | 17.92 |
| R2 | 0.9909 | 0.9935 | 0.9767 | 0.9829 | 0.9879 | 0.9844 | 0.9705 | 0.9891 | 0.9851 | 0.9820 |
| SSE | 0.676 | 1.67 | 2.14 | 4.43 | 13.26 | 0.545 | 1.54 | 2.70 | 3.53 | 34.06 |
| χ2 | 0.054 | 0.872 | 1.23 | 2.44 | 0.634 | 0.231 | 1.11 | 1.13 | 1.79 | 0.543 |
| Sips isotherm | ||||||||||
| qS | 10.76 | 23.68 | 30.39 | 41.25 | 45.21 | 25.79 | 37.15 | 49.21 | 58.14 | 77.56 |
| KS | 0.0631 | 0.2603 | 0.4561 | 0.8075 | 18.99 | 0.1961 | 0.2877 | 0.5274 | 0.9594 | 0.6555 |
| mS | 0.3307 | 0.5017 | 0.6408 | 0.4226 | 0.8174 | 0.3785 | 0.4612 | 0.4613 | 0.4722 | 0.4047 |
| R2 | 0.9928 | 0.9973 | 0.9931 | 0.9881 | 0.9811 | 0.9944 | 0.9748 | 0.9947 | 0.9967 | 0.9865 |
| SSE | 1.87 | 0.68 | 1.48 | 1.09 | 1.957 | 0.466 | 1.51 | 1.88 | 4.16 | 0.4614 |
| χ2 | 0.154 | 0.452 | 0.841 | 0.772 | 0.233 | 0.152 | 0.57 | 1.23 | 1.81 | 0.0629 |
KF ((mg/g)·(L/mg)1/n); qL (mg/g); KL (L/mg); qD (mmol/g); β (mol2/J2); E (kJ/mol); qS (mg/g); KS (L/mg)m