. 2023 Dec 29;63(2):1083–1101. doi: 10.1021/acs.inorgchem.3c03414

Table 5. Cyclic Voltammetry Data for Compounds 2, 3, 10, and 11 versus Fc⁺/Fc in Acetonitrile Solution (5 × 10^–4 M)^a.

compound	E^ox_1/2 (V)	E^red1_1/2 (V)	E^red2_1/2 (V)
2	+0.69 (r)	–1.50 (ir)	–1.73 (ir)
3	+0.68 (r)	–1.49 (ir)	–1.77 (ir)
10	+0.62 (r)	–1.55 (ir)	–1.79 (ir)
11	+0.61 (r)	–1.56 (qr)	–1.80 (qr)

Measured using 0.1 M [ⁿBu₄N][PF₆] as the supporting electrolyte and a scan rate of 0.10 V·s^–1 (r = reversible, qr = quasi-reversible, ir = irreversible). E°(Fc/Fc⁺) = 0.400 V vs SCE.

Table 5. Cyclic Voltammetry Data for Compounds 2, 3, 10, and 11 versus Fc+/Fc in Acetonitrile Solution (5 × 10–4 M)a.

Table 5. Cyclic Voltammetry Data for Compounds 2, 3, 10, and 11 versus Fc⁺/Fc in Acetonitrile Solution (5 × 10^–4 M)^a.