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. 2024 Jan 10;2024:3846392. doi: 10.1155/2024/3846392

Table 3.

Trueness as % recovery and precision as % RSD of repeatability (within-laboratory reproducibility) of target pesticides in tomato matrix spiked at 5, 10, and 40 µg/kg.

S. N. Pesticide Trueness Precision as repeatability (within-laboratory reproducibility)
5 (µg/kg) (n = 6) 10 (µg/kg) (n = 6) 40 (µg/kg) (n = 6) 5 (µg/kg) 10 (µg/kg) 40 (µg/kg)
% recovery % RSD
1 3-Hydroxycarbofuran 93 94 86 4.7 (8.2) 3.2 (4.8) 2.3 (1.7)
2 Acephate 81 80 81 2.4 (8.5) 2.2 (6.4) 1.0 (2.8)
3 Alachlor 89 90 87 3.5 (14.5) 3.6 (5.0) 1.2 (1.6)
4 Aldicarb sulfone 89 90 87 3.8 (8.3) 3.3 (4.9) 1.7 (1.6)
5 Aldicarb sulfoxide 87 88 83 3.6 (5.9) 3.5 (3.5) 1.4 (1.5)
6 Aldicarb 87 83 83 2.0 (8.7) 2.2 (6.5) 1.2 (2.2)
7 Carbaryl 77 83 6.1 (11.7) 5.0 (3.7)
8 Carbendazim 91 86 92 3.1 (9.9) 2.1 (8.3) 1.1 (2.0)
9 Carbofuran 87 85 79 2.5 (12.6) 2.8 (7.5) 2.4 (3.7)
10 Cyprodinil 90 85 83 5.6 (5.5) 3.9 (4.0) 1.1 (1.6)
11 Dimethoate 90 88 88 4.5 (7.0) 2.3 (4.8) 0.9 (1.3)
12 Ethoprophos 91 90 90 2.4 (7.4) 3.0 (4.1) 1.0 (1.2)
13 Imazalil 90 82 78 4.3 (13.3) 4.3 (8.6) 2.9 (4.6)
14 Imidacloprid 104 120 110 5.0 (6.9) 4.9 (4.1) 1.3 (4.6)
15 Kresoxim-methyl 90 90 86 2.5 (6.2) 3.4 (2.8) 1.0 (1.8)
16 Metalaxyl 91 90 89 2.9 (5.6) 2.4 (3.2) 1.2 (1.1)
17 Methidathion 90 93 88 3.2 (6.8) 4.8 (3.6) 1.8 (1.8)
18 Methiocarb 91 93 86 2.1 (4.7) 3.5 (3.1) 1.4 (1.6)
19 Methomyl 90 92 87 5.3 (6.7) 4.0 (4.7) 1.2 (1.9)
20 Monocrotophos 87 90 88 2.9 (6.8) 2.9 (3.2) 1.2 (1.1)
21 Oxamyl 89 93 86 3.9 (7.0) 3.7 (3.2) 1.7 (1.5)
22 Penconazole 88 87 87 3.0 (6.4) 3.2 (4.2) 0.7 (1.4)
23 Propargite 87 83 86 3.1 (5.4) 2.5 (4.5) 1.4 (2.0)
24 Propoxur 90 90 84 1.9 (4.7) 2.1 (1.8) 1.1 (1.3)
25 Thiabendazole 93 88 88 2.4 (6.5) 2.9 (5.1) 1.4 (1.3)
26 Trichlorfon 106 117 113 3.4 (8.2) 4.1 (4.5) 0.8 (3.4)

For carbaryl, a recovery experiment was performed at the 10 µg/kg level.