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. 2024 Jan 4;9(2):2060–2079. doi: 10.1021/acsomega.3c04425

Table 2. Tar Compound Classification Is Based on Solubility, Condensability, And Chemical Composition.

tar class class name property representative compounds
1 gas chromatography (GC)-undetectable very heavy tars cannot be detected by GC subtracting GC-detectable tar from total gravimetric tar
2 heterocyclic aromatics heteroatoms, highly water-soluble compounds pyridine, phenol, cresols, quinoline
3 light aromatic (1 ring) usually, a light HC with a single ring does not pose a problem regarding condensability and solubility toluene, ethylbenzene, xylenes, styrene
4 light PAH (2–3 rings) two- and three-ring compounds condense at low temperatures, even at very low concentrations indene, naphthalene, biphenyl, fluorene, anthracene
5 heavy PAH (4–7 rings) larger than three-ring, these components condense at high temperatures at low concentrations fluoranthene, pyrene, chrysene, perylene, coronene