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. 2024 Jan 18;14(5):3096–3103. doi: 10.1039/d3ra08505h

The synthesis of AMFFs from AcMF using FCRa.

graphic file with name d3ra08505h-u1.jpg
Entry Product code Product(s) Yield (%)
1 1a graphic file with name d3ra08505h-u2.jpg 59b
2 1b graphic file with name d3ra08505h-u3.jpg graphic file with name d3ra08505h-u4.jpg 76c
3 1c graphic file with name d3ra08505h-u5.jpg 82
4 1d graphic file with name d3ra08505h-u6.jpg graphic file with name d3ra08505h-u7.jpg 77c
5 1e graphic file with name d3ra08505h-u8.jpg graphic file with name d3ra08505h-u9.jpg 76c
6 1f graphic file with name d3ra08505h-u10.jpg 81
7 1g graphic file with name d3ra08505h-u11.jpg graphic file with name d3ra08505h-u12.jpg 79c
8 1h graphic file with name d3ra08505h-u13.jpg graphic file with name d3ra08505h-u14.jpg 75c
a

Reaction conditions: AcMF (0.502 g, 2.98 mmol), arene (4 equiv., 11.94 mmol), ZnCl2 (0.250 g, 50 wt%), 120 °C, 3 h.

b

A round-bottomed ACE glass pressure vessel was used.

c

Combined yield of ortho- and para-isomer.