The list of catalytically synthesized hybrid biofuels starting from carbohydrate-derived AcMF.
| |||||
|---|---|---|---|---|---|
| Product codea | Product(s) | Yield (%) | Product codeb | Product(s) | Yield (%) |
| 2a |
|
73 | 3a |
|
84 |
| 2b |
|
76c | 3b |
|
87c |
| 2c |
|
80 | 3c |
|
85 |
| 2d |
|
78c | 3d |
|
81c |
| 2e |
|
76c | 3e |
|
83c |
| 2f |
|
80 | 3f |
|
84 |
| 2g |
|
77c | 3g |
|
84c |
| 2h |
|
75c | 3h |
|
83c |
Reaction conditions: AMFF (0.250 g), Pd(OAc)2 (16 mol%), molecular sieve 4 Å (0.200 g), 140 °C, and 3.5 h.
Reaction conditions: AMFF (0.250 g), 10% Pd/C (0.025 g, 10 wt%), Amberlyst-15 (0.125 g, 50 wt%), hydrogen balloon pressure, room temperature, and 2.5 h.
Combined yield of the ortho- and para-isomers.