Table 2. Determination of Carbaryl Concentration in Vegetable Samples Using Three Types of SPCE-Modified AuNRs Using a Standard Addition Technique.
sample | electrode | amount added (μM) | amount found (μM) | recovery (%) | RSD (%) |
---|---|---|---|---|---|
cabbage | SPCE-A400 | 15 | 14.64 | 102.21 ± 2.72 | 3.44 |
25 | 27.06 | 101.22 ± 3.20 | 3.63 | ||
35 | 34.33 | 99.69 ± 2.86 | 2.72 | ||
SPCE-A600 | 15 | 14.45 | 97.24 ± 3.19 | 3.29 | |
25 | 24.24 | 99.16 ± 3.25 | 3.63 | ||
35 | 35.22 | 98.68 ± 2.91 | 3.52 | ||
SPCE-A800 | 15 | 15.51 | 103.69 ± 3.89 | 2.05 | |
25 | 23.95 | 96.23 ± 1.29 | 4.50 | ||
35 | 36.06 | 102.87 ± 4.27 | 1.95 | ||
cucumber | SPCE-A400 | 15 | 15.18 | 98.52 ± 3.42 | 4.28 |
25 | 24.22 | 99.41 ± 3.65 | 2.25 | ||
35 | 35.30 | 103.60 ± 3.67 | 2.72 | ||
SPCE-A600 | 15 | 15.25 | 98.39 ± 3.29 | 1.00 | |
25 | 25.87 | 107.39 ± 3.49 | 1.69 | ||
35 | 34.93 | 108.14 ± 3.62 | 3.12 | ||
SPCE-A800 | 15 | 14.89 | 101.60 ± 4.38 | 2.32 | |
25 | 26.07 | 95.57 ± 3.26 | 2.51 | ||
35 | 35.94 | 97.65 ± 4.31 | 3.55 | ||
Chinese cabbage | SPCE-A400 | 15 | 15.74 | 109.28 ± 3.69 | 2.62 |
25 | 26.93 | 102.63 ± 5.25 | 3.95 | ||
35 | 35.41 | 99.34 ± 3.75 | 3.71 | ||
SPCE-A600 | 15 | 14.45 | 106.60 ± 3.69 | 4.54 | |
25 | 26.31 | 104.99 ± 3.50 | 2.20 | ||
35 | 35.32 | 104.80 ± 4.68 | 1.44 | ||
SPCE-A800 | 15 | 15.44 | 103.31 ± 4.17 | 1.33 | |
25 | 26.11 | 97.56 ± 4.13 | 1.47 | ||
35 | 33.96 | 104.11 ± 5.12 | 2.01 |