Table 3.
Estimated time scale for deprotonation (tPT) and HAT (tHAT) for 1 and 2.
| t PT | t HAT | |
|---|---|---|
|
| ||
| 1 | ~0.05 s | >~10s |
| 2 | ~2 s | <0.003 s |
| Experimental t(1)/t(2) | ~40:1 | >3×103 :1 |
| Predicted t(1)/t(2) | 20:1 | 3×104 :1 |
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