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. 2024 Jan 12;63(4):1974–1987. doi: 10.1021/acs.inorgchem.3c03708

Table 2. Simulated g-Values of Singly Reduced/Oxidized Complexes 4ac Derived from X-Band EPR Spectroscopy Measurements at 40–80 K.

  4a
4b
4c
  g11 g22 g33 g11 g22 g33 g11 g22 g33
Reduction
Species 1 2.0013 2.0064 2.1043 2.0010 2.0061 2.1040 2.0149 2.0050 2.0868
Species 2 2.0074 1.9963 2.0844 1.9947 2.0071 2.0853      
Species 3       1.9864 2.0061 2.0625      
Oxidation
Species 1 2.0104 2.0140 1.9789 1.9580 2.0044 2.0148 1.9855 2.0133 2.0146
Species 2       1.9867 2.0153 2.0243 1.9666 2.0034 2.0036