Table 2. Simulated g-Values of Singly Reduced/Oxidized Complexes 4a–c Derived from X-Band EPR Spectroscopy Measurements at 40–80 K.
|
4a |
4b |
4c |
|||||||
|---|---|---|---|---|---|---|---|---|---|
| g11 | g22 | g33 | g11 | g22 | g33 | g11 | g22 | g33 | |
| Reduction | |||||||||
| Species 1 | 2.0013 | 2.0064 | 2.1043 | 2.0010 | 2.0061 | 2.1040 | 2.0149 | 2.0050 | 2.0868 |
| Species 2 | 2.0074 | 1.9963 | 2.0844 | 1.9947 | 2.0071 | 2.0853 | |||
| Species 3 | 1.9864 | 2.0061 | 2.0625 | ||||||
| Oxidation | |||||||||
| Species 1 | 2.0104 | 2.0140 | 1.9789 | 1.9580 | 2.0044 | 2.0148 | 1.9855 | 2.0133 | 2.0146 |
| Species 2 | 1.9867 | 2.0153 | 2.0243 | 1.9666 | 2.0034 | 2.0036 | |||