Thermal and mechanical properties of PLA/1, PLA/2, and PLA/4 blends compared to PLA/ATBC blends.
Plasticizer (phr) | T g (°C) | T cc (°C); ΔH (J g−1) | T m (°C); ΔH (J g−1) | tan δ peak Tg (°C) | E′′ peak Tg (°C) | E′ at 25 °C (MPa) | E′′ at 25 °C (MPa) | Tensile strength (MPa) | Strain at break (%) |
---|---|---|---|---|---|---|---|---|---|
PLA | 60 | — | 148–156; 0.2 | 65 | 59 | 1600 | 17 | 60 ± 2 | 3 ± 0.1 |
1 (10) | 46 | 103–125; 12 | 140–153; 12 | 54 | 48 | 1500 | 27 | 50 ± 4 | 3 ± 1 |
1 (15) | 37 | 96–121; 16 | 132–148; 17 | 48 | 42 | 1100 | 34 | 41 ± 4 | 76 ± 43 |
1 (20) | 34 | 93–118; 18 | 131–147; 14 | 43 | 33 | 1300 | 190 | 26 ± 4 | 260 ± 30 |
1 (30) | 24 | 87–120; 12 | 124–142; 14 | 36 | 26 | 710 | 310 | 30 ± 2 | 470 ± 40 |
1 (40) | 14 | 82–111; 10 | 118–138; 12 | 28 | 17 | 270 | 140 | 21 ± 3 | 150 ± 20 |
2 (10) | 43 | 100–121; 17 | 136–151; 17 | 58 | 52 | 1600 | 38 | 42 ± 3 | 4 ± 2 |
2 (20) | 31 | 94–110; 19 | 129–145; 16 | 45 | 36 | 1400 | 180 | 22 ± 3 | 440 ± 160 |
2 (30) | 24 | 90–110; 14 | 125–143; 13 | 37 | 27 | 820 | 310 | 14 ± 6 | 540 ± 100 |
2 (40) | 15 | 87–111; 7 | 123–138; 8 | 49, 30 | 23 | 580 | 260 | — | — |
4 (10) | 49 | 107–140; 20 | 140–156; 18 | 54 | 49 | 1500 | 35 | 21 ± 7 | 31 ± 13 |
4 (15) | 41 | 96–116; 30 | 143–151; 27 | 39 | 30 | 680 | 150 | 17 ± 0.4 | 180 ± 6 |
4 (20) | 35 | 94–122; 28 | 142–149; 24 | 43 | 34 | 1300 | 170 | 9 ± 1 | 110 ± 20 |
4 (30) | 25 | 88–110; 23 | 123–145; 20 | 36 | — | 320 | 49 | — | — |
4 (40) | 21 | 83–103; 26 | 134–143; 23 | 33 | — | 360 | 60 | — | — |
ATBC (10) | 46 | 98–125; 25 | 139–155; 25 | 52 | 46 | 2000 | 43 | 52 ± 3 | 5 ± 3 |
ATBC (15) | 37 | 95–119; 30 | 135–154; 26 | 47 | 38 | 1500 | 100 | 26 ± 0.4 | 220 ± 14 |
ATBC (20) | 30 | 87–100; 28 | 141–152; 27 | 42 | 32 | 840 | 120 | 27 ± 1 | 300 ± 57 |