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. 2024 Feb 5;14(7):4702–4716. doi: 10.1039/d3ra08922c

Thermal and mechanical properties of PLA/1, PLA/2, and PLA/4 blends compared to PLA/ATBC blends.

Plasticizer (phr) T g (°C) T cc (°C); ΔH (J g−1) T m (°C); ΔH (J g−1) tan δ peak Tg (°C) E′′ peak Tg (°C) E′ at 25 °C (MPa) E′′ at 25 °C (MPa) Tensile strength (MPa) Strain at break (%)
PLA 60 148–156; 0.2 65 59 1600 17 60 ± 2 3 ± 0.1
1 (10) 46 103–125; 12 140–153; 12 54 48 1500 27 50 ± 4 3 ± 1
1 (15) 37 96–121; 16 132–148; 17 48 42 1100 34 41 ± 4 76 ± 43
1 (20) 34 93–118; 18 131–147; 14 43 33 1300 190 26 ± 4 260 ± 30
1 (30) 24 87–120; 12 124–142; 14 36 26 710 310 30 ± 2 470 ± 40
1 (40) 14 82–111; 10 118–138; 12 28 17 270 140 21 ± 3 150 ± 20
2 (10) 43 100–121; 17 136–151; 17 58 52 1600 38 42 ± 3 4 ± 2
2 (20) 31 94–110; 19 129–145; 16 45 36 1400 180 22 ± 3 440 ± 160
2 (30) 24 90–110; 14 125–143; 13 37 27 820 310 14 ± 6 540 ± 100
2 (40) 15 87–111; 7 123–138; 8 49, 30 23 580 260
4 (10) 49 107–140; 20 140–156; 18 54 49 1500 35 21 ± 7 31 ± 13
4 (15) 41 96–116; 30 143–151; 27 39 30 680 150 17 ± 0.4 180 ± 6
4 (20) 35 94–122; 28 142–149; 24 43 34 1300 170 9 ± 1 110 ± 20
4 (30) 25 88–110; 23 123–145; 20 36 320 49
4 (40) 21 83–103; 26 134–143; 23 33 360 60
ATBC (10) 46 98–125; 25 139–155; 25 52 46 2000 43 52 ± 3 5 ± 3
ATBC (15) 37 95–119; 30 135–154; 26 47 38 1500 100 26 ± 0.4 220 ± 14
ATBC (20) 30 87–100; 28 141–152; 27 42 32 840 120 27 ± 1 300 ± 57