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. 2024 Jan 11;12(6):3180–3208. doi: 10.1039/d3ta05972c

Properties of select multichromophoric photoswitches compared to analogous single chromophores.

Photoswitch ref. Number of chromophore units λ onset/nm QY t 1/2 ΔH/kJ mol−1 Energy density/kJ kg−1
graphic file with name d3ta05972c-u1.jpg 27 1 374b 0.39 22 h 102 469
graphic file with name d3ta05972c-u2.jpg 13 2 411c 0.94 4.33 h (QC–QC) 183.3 514.2
graphic file with name d3ta05972c-u3.jpg 27 1 358b 0.58 1320 h 122 629
graphic file with name d3ta05972c-u4.jpg 13 2 400c 0.73 10.6 days (QC–QC) 237.9 (calculated) 771.4 (calculated)
graphic file with name d3ta05972c-u5.jpg 31 2 370c 0.56 2 days 175 678
graphic file with name d3ta05972c-u6.jpg 101 1 426b 0.53 72 h 152 575
graphic file with name d3ta05972c-u7.jpg 25 2 466b 0.77 12 h (QC–QC) 146.8 326
graphic file with name d3ta05972c-u8.jpg 100 1 390b 0.61 0.22 days 114 571
graphic file with name d3ta05972c-u9.jpg 32 2 420a 0.44 10.7 min
graphic file with name d3ta05972c-u10.jpg 69 1 347 (n–πa band) d 0.23 37.7 min 54.1 255
graphic file with name d3ta05972c-u11.jpg 69 2 357a 0.11 28.1 h 94.2 272
graphic file with name d3ta05972c-u12.jpg 69 3 362a 0.09 20.5 h 116 242
graphic file with name d3ta05972c-u13.jpg 87 1 355 (λmax)e 216 min
graphic file with name d3ta05972c-u14.jpg 87 2 408 (λmax)e
graphic file with name d3ta05972c-u15.jpg 87 2 365 (λmax)e 160 min
a

Values extracted manually from the reported spectra. Solvents used for measurements.

b

Toluene.

c

Cyclohexane.

d

THF.

e

MeCN.