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. 2024 Feb 8;14(8):5085–5131. doi: 10.1039/d3ra07518d

Recent developments in polymer-based PSCs.

Category Methodology/technique Significance/improvements References
Interfacial modification Device encapsulation, inverted orientation Enhanced durability 157, 176 and 177
Intrinsic alteration Reducing moisture–corrosion Increased stability of perovskites 158 and 178
Intergranular interface optimization Enhancing crystallinity Better charge separation and transportation; however, higher defect density 160–163, 179 and 180
Polymer-based PSCs Use of PEO, PMMA, PEI, PVP Enhanced resilience and PCE; however, may reduce the crystallinity or photoelectric property of the perovskite 164–166 and 181–185
Dendritic polymers Use of dendritic polymers Enhanced stability and effectiveness 167 and 186
PAMAM dendrimers Polyamidoamine (PAMAM) dendrimers Improved PCE to 42.60%, enhanced perovskite intergranular interactions 168
NPE buffer layers Nonconjugated polymer electrolytes (NPEs) Improved PCE in both N–I–P (14.71%) and P–I–N (13.79%) configurations 169
PEDOT:PSS HTLs CuSCN-modified PEDOT:PSS HTL Improved PCE to 15.30%, exceptional longevity. However PEDOT:PSS is acidic in nature 174
NPB buffer layer NPB as a buffer layer Reduced electron–hole recombination, improved PCE to 18.40% 175