Table 3.
Optical data of 2a-g in solid films at room temperature.
| BPhTC | λabsa/nm |
Egopt/eV | λemb/nm |
Stokes shift/cm−1 | Fluorescencec | |
|---|---|---|---|---|---|---|
| λ1 | λ2 | |||||
| 2a | 367 | 526 | 2.18 | 607 | 2537 | 1456 |
| 2b | 381 | 522 | 2.22 | 606 | 2655 | 3538 |
| 2c | 365 | 523 | 2.19 | 592 | 2229 | 1111 |
| 2d | 379 | 522 | 2.20 | 604 | 2601 | 3702 |
| 2e | 364 | 521 | 2.19 | 575 | 1806 | 1742 |
| 2f | 375 | 527 | 2.19 | 562 | 1182 | 870 |
| 2g | 372 | 518 | 2.22 | 584 | 2182 | 1954 |
Absorption of thin solid films.
Emission of thin solid film exited at the absorption maximum (λ2).
Measured from experimental emission spectra as area under the curve in area units.