Table 2. Mechanism Model Fitting Results under Pure Oxygen Conditions.
numbering | function name | reaction mechanism | F(α) | f(α) | R1 (first stage) | R2 (second stage) | R3 (third stage) | R4 (fourth stage) |
---|---|---|---|---|---|---|---|---|
1 | Maple one-line rule, first order | stochastic nucleation and subsequent growth | –ln (1 – α) | 1 – α | 0.9837 | 0.9807 | 0.8350 | 0.9580 |
2 | second order | chemical reaction, deceleration shape α-t curve | (1 – α)−1 – 1 | (1 – α)2 | 0.9644 | 0.9418 | 0.8547 | 0.9504 |
3 | shrinking cylinder(area) | phase boundary reaction (cylindrical symmetry) | 1 – (1 – α)0.5 | 2 × (1 – α)0.5 | 0.9612 | 0.9994 | 0.7878 | 0.9538 |
4 | 2/3 order | chemical reaction | (1 – α)−0.5 | 2 × (1 – α)1.5 | 0.9737 | 0.9586 | 0.8486 | 0.9535 |
5 | constricted globose | phase boundary reaction (spherical symmetry) | 1–(1−α)1/3 | 3 × (1 – α)2/3 | 0.9802 | 0.9957 | 0.8121 | 0.9595 |