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. 2024 Jan 22;9(5):5728–5733. doi: 10.1021/acsomega.3c08380

Table 2. Mechanism Model Fitting Results under Pure Oxygen Conditions.

numbering function name reaction mechanism F(α) f(α) R1 (first stage) R2 (second stage) R3 (third stage) R4 (fourth stage)
1 Maple one-line rule, first order stochastic nucleation and subsequent growth –ln (1 – α) 1 – α 0.9837 0.9807 0.8350 0.9580
2 second order chemical reaction, deceleration shape α-t curve (1 – α)−1 – 1 (1 – α)2 0.9644 0.9418 0.8547 0.9504
3 shrinking cylinder(area) phase boundary reaction (cylindrical symmetry) 1 – (1 – α)0.5 2 × (1 – α)0.5 0.9612 0.9994 0.7878 0.9538
4 2/3 order chemical reaction (1 – α)−0.5 2 × (1 – α)1.5 0.9737 0.9586 0.8486 0.9535
5 constricted globose phase boundary reaction (spherical symmetry) 1–(1−α)1/3 3 × (1 – α)2/3 0.9802 0.9957 0.8121 0.9595