Table 3. Reaction Mechanism Function for Each Stage.
reaction stage | reaction temperature (°C) | f(α) | function name | reaction mechanism |
---|---|---|---|---|
1 | 67–114 | f = 1 – α | Maple one-line rule, first order | stochastic nucleation and subsequent growth |
2 | 220–286 | f = 2 × (1 – α)0.5 | shrinking cylinder (area) | phase boundary reaction (cylindrical symmetry) |
3 | 417–432 | f = (1 – α)2 | second order | chemical reaction, deceleration shape α–t curve |
4 | 455–484 | 3 × (1 – α)2/3 | constricted globose | phase boundary reaction (spherical symmetry) |