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. 2024 Jan 22;9(5):5728–5733. doi: 10.1021/acsomega.3c08380

Table 3. Reaction Mechanism Function for Each Stage.

reaction stage reaction temperature (°C) f(α) function name reaction mechanism
1 67–114 f = 1 – α Maple one-line rule, first order stochastic nucleation and subsequent growth
2 220–286 f = 2 × (1 – α)0.5 shrinking cylinder (area) phase boundary reaction (cylindrical symmetry)
3 417–432 f = (1 – α)2 second order chemical reaction, deceleration shape α–t curve
4 455–484 3 × (1 – α)2/3 constricted globose phase boundary reaction (spherical symmetry)