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. 2024 Jan 22;9(5):5406–5417. doi: 10.1021/acsomega.3c06753

Table 1. Thermal Properties of PLA and PLA/ILs in the 1st and 2nd Heating Cycles.

samples 1st heating 2nd heating
Tg Tcc Tm ΔHm Xc (%) Tg Tcc Tm ΔHm Xc (%)
PLA 59.2 ± 0.2 94.3 ± 0.5 150.8 ± 0.3 26.2 ± 0.5 27.9 ± 0.5 59.5 ± 0.2 123.3 ± 0.3 148.7 ± 0.4 19.5 ± 0.6 20.8 ± 0.3
PLA/3di 60.0 ± 0.2 87.7 ± 0.4 149.0 ± 0.5 29.1 ± 0.4 32.0 ± 0.4 58.4 ± 0.3 120.0 ± 0.4 148.1 ± 0.2 30.1 ± 0.4 33.1 ± 0.4
PLA/5di 56.0 ± 0.3 87.5 ± 0.4 150.3 ± 0.4 32.7 ± 0.3 36.7 ± 0.3 56.9 ± 0.3 118.7 ± 0.5 147.4 ± 0.3 29.2 ± 0.5 32.8 ± 0.5
PLA/10di 54.6 ± 0.4 85.8 ± 0.5 150.2 ± 0.2 31.2 ± 0.2 37.0 ± 0.2 54.2 ± 0.5 123.5 ± 0.6 145.9 ± 0.7 21.0 ± 0.7 24.9 ± 0.7
PLA/3tri 59.4 ± 0.3 86.7 ± 0.4 150.1 ± 0.3 32.1 ± 0.6 35.3 ± 0.6 57.4 ± 0.2 119.1 ± 0.7 147.6 ± 0.4 27.1 ± 0.3 29.8 ± 0.3
PLA/5tri 57.6 ± 0.3 87.5 ± 0.2 150.2 ± 0.2 31.0 ± 0.3 34.8 ± 0.3 58.0 ± 0.2 120.8 ± 0.5 147.3 ± 0.3 21.1 ± 0.6 23.7 ± 0.6
PLA/10tri 55.0 ± 0.5 101.4 ± 0.5 149.9 ± 0.4 31.5 ± 0.2 37.3 ± 0.2 54.1 ± 0.4 118.8 ± 0.3 146.7 ± 0.4 25.7 ± 0.4 30.5 ± 0.4
PLA/3tetra 57.7 ± 0.3 88.1 ± 0.6 150.9 ± 0.5 34.2 ± 0.4 37.6 ± 0.4 58.1 ± 0.3 121.6 ± 0.4 148.3 ± 0.2 21.7 ± 0.5 23.9 ± 0.5
PLA/5tetra 57.4 ± 0.1 87.9 ± 0.5 150.1 ± 0.5 31.1 ± 0.5 34.9 ± 0.5 57.5 ± 0.2 119.4 ± 0.4 146.8 ± 0.5 24.6 ± 0.3 27.6 ± 0.3
PLA/10tetra 55.1 ± 0.4 90.8 ± 0.7 150.1 ± 0.3 29.7 ± 0.3 35.2 ± 0.3 55.1 ± 0.5 122.3 ± 0.2 147.8 ± 0.2 19.5 ± 0.2 23.1 ± 0.2