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a) TORC-mediated assembly of aldehyde- and hydrazide-functionalized peptide oligomers into topologically diverse quaternary assemblies including macrocycles, zipper-like structures, multiloop macrocycles, and ladder polymers. b) This work has initiated the current research goal of designing sequence-specific TORC oligomers with a defined TORC code that templates the macromolecular assembly in an analogous manner to DNA.
