PFO |
q
t
= qe(1 − e−K1t) (7) |
- qt and qe (mg g−1): the adsorbed amount of copper at any time “t” and at the end, respectively |
Fig. 8
|
PSO |
(8) |
- K1 (min−1), K2 (g (min−1 mg−1)), kAV (min−1): the constants of PFO, PSO and Avrami, respectively |
Fig. 8
|
Elovich |
(9) |
- α (mg (g−1 min−1)): the sorption rate constant associated with the covered surface of chemisorption in the Elovich kinetic model |
Fig. 8
|
- β (mg g−1): the desorption constant associated with the reaction energy of chemisorption in the Elovich kinetic model |
Avrami |
(10) |
- nAV: the Avrami constant exponent (dimensionless) |
Fig. 8
|
Intraparticle diffusion |
(11) |
- Kint (mg (g−1 min−1/2)): rate constant of the Weber–Morris model |
Fig. 8
|
-C (mg g−1): constant depending on the boundary layer thickness in the Weber–Morris kinetic model |
Langmuir |
(12) |
- Qmax (mg g−1): maximum adsorption capacity of Langmuir |
Fig. 9
|
- KL (L mg−1): the constants of Langmuir |
Freundlich |
(13) |
- KF [(mg g−1)/(mg L−1)1/n]: the constants of Freundlich |
Fig. 9
|
- nF: dimensionless Freundlich parameter of intensity |
Redlich–Peterson |
(14) |
-KRP (L g−1) and aRP (mg L−1)−g: the Redlich–Peterson equilibrium constants, respectively |
Fig. 9
|
- g: the dimensionless Redlich–Peterson exponent should be ≤1 |
Sips |
(15) |
- qs and Qmax (mg g−1): the maximum adsorption capacity of Sips and Liu isotherms, respectively |
Fig. 9
|
Liu |
(16) |
- KS and Kg (L mg−1): the Sips and Liu equilibrium constants, respectively |
Fig. 9
|
- ns and nL: the dimensionless Sips and Liu exponents, respectively |