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. 2024 Feb 9;14(8):5276–5289. doi: 10.1039/d3ra08678j

The kinetic and isotherm modelling equations and parameters of Cu(ii) adsorbed onto SPAC.

Model Equation Plot Parameters
PFO q t = qe(1 − eK1t) (7) - qt and qe (mg g−1): the adsorbed amount of copper at any time “t” and at the end, respectively Fig. 8
PSO Inline graphic (8) - K1 (min−1), K2 (g (min−1 mg−1)), kAV (min−1): the constants of PFO, PSO and Avrami, respectively Fig. 8
Elovich Inline graphic (9) - α (mg (g−1 min−1)): the sorption rate constant associated with the covered surface of chemisorption in the Elovich kinetic model Fig. 8
- β (mg g−1): the desorption constant associated with the reaction energy of chemisorption in the Elovich kinetic model
Avrami Inline graphic (10) - nAV: the Avrami constant exponent (dimensionless) Fig. 8
Intraparticle diffusion Inline graphic (11) - Kint (mg (g−1 min−1/2)): rate constant of the Weber–Morris model Fig. 8
-C (mg g−1): constant depending on the boundary layer thickness in the Weber–Morris kinetic model
Langmuir Inline graphic (12) - Qmax (mg g−1): maximum adsorption capacity of Langmuir Fig. 9
- KL (L mg−1): the constants of Langmuir
Freundlich Inline graphic (13) - KF [(mg g−1)/(mg L−1)1/n]: the constants of Freundlich Fig. 9
- nF: dimensionless Freundlich parameter of intensity
Redlich–Peterson Inline graphic (14) -KRP (L g−1) and aRP (mg L−1)g: the Redlich–Peterson equilibrium constants, respectively Fig. 9
- g: the dimensionless Redlich–Peterson exponent should be ≤1
Sips Inline graphic (15) - qs and Qmax (mg g−1): the maximum adsorption capacity of Sips and Liu isotherms, respectively Fig. 9
Liu Inline graphic (16) - KS and Kg (L mg−1): the Sips and Liu equilibrium constants, respectively Fig. 9
- ns and nL: the dimensionless Sips and Liu exponents, respectively