Table 1. MOFs with Different Lewis Acidic Functionalities and Their Utilities toward Catalysisa.
| Sr. No. | MOF Compound | Lewis acidic metal site | Labile solvent | Catalytic reaction | Ref |
|---|---|---|---|---|---|
| 1 | Zr6-fBDC and Zr6-fBPDC | Zr4+ | H2O | Arene C–H Iodination | (258) |
| 2 | Zr6OTf-BTB | Zr4+ | - | Povarov Reactions | (259) |
| 3 | [Zn2(TBIB)2(HTCPB)2]·9DMF·19H2O | Zn2+ | - | Cycloaddition of CO2 | (260) |
| Friedländer Reaction | |||||
| 4 | MOF-525, PCN-222 and PCN-224 | Zr2+, Mn2+, Zn2+ | - | Cycloaddition of CO2 | (261) |
| 5 | M-NU-1008 | M = Zr4+, Hf, Th, Ce3+ | H2O | Cycloaddition of CO2 | (262) |
| 6 | ZIF-8 | Zn2+ | - | Epoxide Hydroxylation | (263) |
| 7 | Tb(BTC)(H2O)3(DMF)1.1 | Tb3+ | H2O, DMF | Synthesis of β-Aminoalcohols | (264) |
| 8 | Er(BTC)(H2O)·(DMF)1.1 | Er3+ | H2O, DMF | Hantzsch Coupling and Tetrahydro-4H-Chromene Synthesis | (265) |
| 9 | [Ba2(BDPO)(H2O)]·DMA | Ba2+ | H2O | Cycloaddition of CO2 | (266) |
| 10 | NH2-MIL-101/PAN | Cr3+ | - | Friedel–Crafts Acylation of Anisole | (267) |
| Esterification reaction | |||||
| 11 | Cu(II)-MOF | Cu2+ | H2O | Cycloaddition of CO2 | (268) |
| 12 | Zr6O4(OH)4(OAc)2.4[M(PNNNP)X]2.4 [M = Pd, Pt] | Zr4+, Pd(I), Pt(I) | - | Hydroamination of o-Alkynyl Aniline | (269) |
| 13 | [Zn2(iso)2(bpy)2] | Zn2+ | DMF | Cycloaddition of CO2 | (270) |
| 14 | [Zn(BPBA)Cl]·5H2O | Zn2+ | H2O | Cyclization of ortho-Substituted Diaminonaphthalene to Naphthimidazole | (58) |
| 15 | Ce-doping MIL-88A(Fe) | Ce3+, Fe3+ | - | Catalytic Ozonation | (271) |
| 16 | Pd(II)/UIO-66 (Zr), Pd(II)/MIL-101 (Cr) and Pd(II)/MOF-5 (Zn) | Pd2+, Cr3+, Zn2+ | H2O | CO Esterification to Dimethyl Carbonate | (272) |
| 17 | UiO-66 | Zr4+ | H2O | Aldose Sugars to Polyhydroxyalkyl and C-Glycosyl Furans | (273) |
| 18 | [Cd3(BDC)3(OPP)(DMF)2]·2DMA | Cd2+ | DMF | Hantzsch Reaction | (274) |
| 19 | Cu-BTC(MOF-199) | Cu2+ | - | Aerobic Oxidative Synthesis of Imines | (275) |
| 20 | MIL-101(Fe,Sc) | Fe3+, Sc3+ | - | Glucose to 5-Hydroxymethyl Furfural | (276) |
| 21 | Al-ITQ-Br, Al-ITQ-NO2, L-MOF-EB L-MOF-AB | Fe3+, Al3+ | - | Oxidation of Thiophenol to Diphenyldisulfide | (277) |
| 22 | [Eu(tctb)(H2O)] | Eu3+ | H2O | Diamines to Benzimidazoles | (278) |
| 23 | [M6(TATAB)4(DABCO)3(H2O)3]·12DMF·9H2O | M = Co2+, Ni2+ | H2O | Chemical Fixation of CO2 | (279) |
| 24 | MixUMCM-1-NH2. | Zn2+ | - | Aldol–Tishchenko Reaction | (280) |
| 25 | [In3(NIPH)3(HNIPH)(OH)2]·4H2O | In3+ | -H2O | Multicomponent Strecker Reactions | (281) |
| 26 | [Mn2(TDP)(H2O)2]·3H2O·3DMF | Mn2+ | -H2O | Chemical Fixation of CO2 | (282) |
| 27 | [Cu6(TADIPA)3(DABCO)(H2O)2(DMF)2]·13H2O [Cu6(TADIPA)3(H2O)6]·16H2O·8DMF | Cu2+ | -H2O, DMF, DMA | Chemical Fixation of CO2 | (283) |
| [H3O][Cu6(TPTA)3(DMA)4(COO)]·12H2O·7DMA | |||||
| [Cu6(C17O9N2H8)3(C6H12N2)(H2O)2(DMF)2]·3DMF·8H2O | |||||
| 28 | UiO-66-TA | Zr4+ | -H2O | Hydrogenation of Cinnamaldehyde | (284) |
| 29 | MIL-101(Cr)-LP | Cr3+ | - | Reduction of Imine | (285) |
| 30 | MIL-101(Cr) MOF | Cr3+ | - | glucose to fructose | (286) |
| 31 | [Zn3(Hbtc)2(atz)2]·CH3CN·2CH3OH [Co3(Hbtc)2(atz)2]·H2O·2DMF | Zn2+ Co2+ | - | Coupling of CO2 and Epoxides | (287) |
| 32 | [Zn(bix)]{V2O6}(V-Zn-MOF | Zn2+ | - | Cyanosilylation Reaction of Aldehydes | (288) |
| 33 | [Dy3(data)3·2DMF]·DMF | Dy3+ | DMF | Chemical Fixation of CO2 | (155) |
| 34 | Cu-MOF | Cu2+ | - | Catalytic CO2 Fixation | (289) |
| 35 | [Cd(bpp)(L)(H2O)]·DMF | Cd2+ | -H2O | Strecker Reaction | (290) |
| 36 | Cr-UiO-66-CAT | Zr4+ | - | Oxidation of Alcohols to Ketones | (85) |
H2fBDC = 2,3,5,6-tetrafluoro-1,4-benzenedicarboxylic acid; H2fBPDC = 2,2′,3,3′,5,5′,6,6′-octafluoro-4,4′-biphenyldicarboxylic acid; TBIB = 1,3,5-tri(1H-benzo[d]imidazol-1-yl)benzene); H3TCPB = 1,3,5-tris(4′-carboxyphenyl-)benzene; BTC = 1,3,5-benzenetricarboxylate; DMF = N,N-dimethylformamide; PAN = polyacrylonitrile; PNNNP = 2,6-(HNPAr2)2C5H3N; Ar = p-C6H4CO2–; X = Cl–, I–; iso = isophthalic acid; bpy = 4,4-dipyridyl; BPBA = 3,5-bis(4-oxo-4H-pyridin-1-yl)-benzoate; OPP = N,N′-(oxybis(4,1-phenylene))bis(1-(pyridin-4-yl)methanimine); H2BDC = terephthalic acid; H3tctb = tris(p-carboxylic acid)tridurylborane; H3TATAB = 4,4′,4″-s-triazine-1,3,5-triyl-tri-p-aminobenzoic acid; DABCO = 1,4-diazabicyclo[2.2.2]octane; BDC = 1,4-benzenedicarboxylate; ABDC = 2-amino-1,4-benzenedicarboxylate, btb = 4,4′,4″,-benzene-1,3,5-triyl-trisbenzoic acid; H2NIPH = 5-nitroisophthalic acid; H4TPTA = 1,1′,3′,1″-terphenyl-3,3′′,5,5′-tetracarboxylic acid; H4CBDA = 5,5′-(carbonylbis(azanediyl)) diisophthalic acid; TA = terephthalic acid; LP = Lewis pair; bix = 1,4-bis(imidazole-1-ylmethyl)benzene; 2,5-data = 2,5-diamino-terephthalate; H2L = 5-(1-oxo-2,3-dihydro-1H-inden-2-yl)isophthalic acid; H2L = 4,4′-(dimethylsilanediyl)bis-benzoic acid; bpp = 1,3-bis(4-pyridyl)propane.