Table 3. MOFs with Different Basic Functionalities and Their Utility toward Catalysisa.
| Sr. No. | MOF Compound | Ligand responsible for basicity | Catalytic reaction | Ref |
|---|---|---|---|---|
| 1 | [Cd(C16H10N2O8S)(H2O)] | -NH | Knoevenagel Condensation | (110) |
| 2 | [(Nd2(TATMA)2·4DMF·4H2O]n | -N | Knoevenagel Condensation | (111) |
| 3 | [H2N(CH3)2]·[Zn4(L)1.5(ad)3(H2O)2)]·4DMF | -NH2 | Knoevenagel Condensation | (112) |
| 4 | {[Zn2(D-CAM)2(L)]·MeOH·2H2O}n | -NH | Ring-Opening of Spiro-Epoxyoxindoles | (113) |
| 5 | Co2(bdda)1.5(OAc)1·5H2O | -NH | Henry Reactions | (114) |
| 6 | [Zn(OBA)(BPDB)0.5]n·2DMF | -N | Knoevenagel Condensation | (115) |
| 7 | [Y3(μ3-O)2(μ3OH)(H2O)2(BTCTBA)2]·2[(CH3)2NH2]·5DMF·C6H5Cl·4H2O | C=O–N–H | Knoevenagel Condensation | (116) |
| 8 | [Zn2(hfipbb)2(4-bpdh)]·0.5DMF and [Zn2(hfipbb)2(4-bpdb)]·2DMF | -N=N- | Knoevenagel Condensation | (117) |
| 9 | UiO-67-BPY@UiO-66 | -Nbpy | Knoevenagel Condensation | (118) |
| 10 | [Zn2(3-tpom)(L)2]·2H2O | -O | Strecker Reaction | (119) |
| 11 | [Cu2(L)(H2O)2]·(3DMF)(4H2O) | -N | Henry Reactions | (120) |
| 12 | [(CH3)2NH2+]2[Zn3((μ3-O))(L)2(H2O)]·4DMF·2H2O | -NH2 | Chemical Fixation of CO2 | (121) |
| Biginelli Reactions | ||||
| 13 | [Cu2(L)(H2O)2]·(5DMF)(4H2O) | -NH2 | Biginelli Reactions | (122) |
| 14 | [CoL(H2O)3]·2NO3 | -N | Knoevenagel Condensation | (123) |
| 15 | UiO-67@Fe | -Nbpy | Morita–Baylis–Hillman Reaction | (124) |
| 16 | ZIF-8, ZIF-67 | -Nim | Knoevenagel Condensation | (125) |
| 17 | MIL-125-NH2 | -NH2 | Plasticizers Syntheses | (126) |
| 18 | SB-Cu1 | -N | N-Arylation | (127) |
| 19 | NH2cCo-PYI1 and NH2cCo-PYI2 | -NH2 | Aldol and Knoevenagel Condensations | (128) |
Nic = nicotinamide; pic = picrate; H3dcp = 3,5-pyrazoledicarboxylic acid; DMA = N,N-dimethylacetamide; ad = adenine; H4L = 5,5′-(1,3,6,8-tetraoxobenzo phenanthroline-2,7-diyl)bis-1,3-benzenedicarboxylic acid; H3TATMA = 4,4,4″-s-triazine-1,3,5-triyltri-m-aminobenzoate; L = N′-(pyridin-4-ylmethylene)isonicotinohydrazide; bdda: 4,4′-[benzene-1,4-diylbis(methylidenenitrilo)] dibenzoic acid); H3BTCTBA = 4,4′,4″-[1,3,5-benzenetriyltris(carbonylimino)]trisbenzoic acid; 4-bpdb = 1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene; 4-bpdh = 2,5-bis(4-pyridyl)-3,4-diaza-2,4-hexadiene; H2L = dicarboxylic acid 4,4′-(dimethylsilanediyl)bis-benzoic acid; 3-tpom = tetrakis(3-pyridyloxymethylene)methane; H4L = 5,5′-(piperazine-1,4-diyl)diisophthalic acid; L = 4-(trifluoromethyl)aniline, 1-bromo-3,5-dimethylbenzene; L = tris(4-(4H-1,2,4-triazol-4-yl)phenyl)amine; PYI = pyrrolidine-2-yl-imidazole.