Table 4. MOFs with Bi-/Multifunctionality and Their Use in Catalysisa.
| Sr. No. | MOF Compound | Reactive site | Catalytic reaction | Ref | |
|---|---|---|---|---|---|
| 1 | MIL-101(Cr)-N(CH2PO3H2)2 | Cr(III) Phosphonates, -NH2 | Synthesis of N-Amino-2-Pyridone and Pyrano [2,3-c]Pyrazole Derivatives | (139) | |
| 2 | [Zn2(TCA)(BIB)2.5]·(NO3) | Zn (II), NTCA | Cycloaddition of CO2 | (140) | |
| 3 | [Mn2(DPP)(H2O)3]·6H2O | Mn (II), -Npyridine | Cycloaddition of CO2 | (141) | |
| 4 | [Zn(1,4-NDCA)(3-BPDB)0.5]·(DMF)(MeOH) [Cd4(1,4-NDCA)4(3-BPDB)4]·2(DMF) | Zn(II)Cd(II), -N=N- | Friedländer Reaction | (142) | |
| Michael Addition | |||||
| 5 | [M3(5-CFIA)2(8H2O)]·H2O | Cd(II), Mn(II), -NH | Aldol Condensation | (143) | |
| β-Enamination Reactions | |||||
| 6 | [Zn(HL)2] | Zn (II), -Ntriazole | Knoevenagel Condensation | (50) | |
| 7 | [Zn15(L-NH2)6(HL-NH2)6(LNA)4(HLNA)2(μ3–OH)2] | Zn(II), -NH2 | Knoevenagel Condensation | (144) | |
| 8 | SulP1/SulP2-MOF-808(Hf) | Hf(IV), Phosphonate | Reductive Amination and Hydroaminomthylation Reactions | (145) | |
| 9 | ED/MIL-101(Cr) | Cr (III), -NH2 | Hantzsch Condensation Reaction | (146) | |
| 10 | Zn-Bp-BTC MOF | Zn(II), -Nbipyridine | Knoevenagel Condensation | (147) | |
| Multicomponent Reaction | |||||
| Benzimidazole Synthesis | |||||
| 11 | Lysine - (Zr)MOF-808 | Zr(IV),- NH2 | Henry Condensation and Friedel/Crafts Type Alkylation | (148) | |
| 12 | C32H40Fe2N2S4Zn | Zn(II), -NH2 | One Pot Synthesis of Chromene and Imidazopyrimidine Derivatives | (149) | |
| 13 | Co/Ni2(BTC)(OH)(4-TPT)2(H2O)·(DMA)0.5(H2O)2 | Co(II)Ni(II), Npyridyl | Oxidation–Knoevenagel Cascade Reaction | (150) | |
| 14 | Cu3TATAT | Cu(II), -NH, N | Aerobic Oxidation/Knoevenagel Condensation | (151) | |
| 15 | Hf/Zr MOF-808 | Hf(IV)Zr(IV) Defective -OH | Tandem N-Alkylation of Amines with Benzyl Alcohol | (152) | |
| 16 | PMoV2@DETA-MIL-101 | Cr(III)PMoV2, -NH2 | Aerobic Oxidation-Knoevenagel One-Pot Reaction | (153) | |
| 17 | CuI@UiO-67-IM | CuI | One-Pot Azide–Alkyne Cycloaddition | (154) | |
| 18 | [Dy3(data)3·2DMF]·DMF, NH2-TMU-73 | Dy(III), -NH2 | Solvent-Free Conversion of CO2 to Cyclic Carbonates | (155) | |
| 19 | Co-NDTz and Co-NDPhTz | Co(II), -Ntetrazole | Tandem Oxidation and CO2 Conversion Reactions | (156) | |
| 20 | [Cu2Br2(pypz)]n·nH2O | Cu(II), Br– | Homocoupling of Arylboronic Acids and Epoxidation of Olefins | (157) | |
| 21 | [Cd(PBA)(DMF)]·DMF | Cd(II), -NH | Cyanosilylation and Hydroboration | (158) | |
| 22 | Ni-DDIA | Ni(II)-COOH | Biginelli Reaction | (94) | |
| 23 | MIL-101(Cr)-NH–CO-Pr-COOH | Cr(III)-COOH | Synthesis of Quinazolin-(4H)-1-one Derivatives | (68) | |
| 24 | MIL-101(Cr)-SO3H | Cr(III)-SO3H | Hydrogenation of Imines | (159) | |
| 25 | Arg2PTA/ZIF-8 | Zn2+, -Nimidazole | Production of Biodiesel from Insect Lipid | (160) |
Abbreviations: data = 2,5-data = 2,5-diamino-terephthalate; MA = melamine; ED = ethylene diamine; DPP = 2,6-di(2,4-dicarboxyphenyl)-4-(pyridine-4-yl)pyridine; H8L = tetraphenylsilane tetrakis-4-phosphonic acid; H3TCA = tricarboxy triphenyl amine; BIB = 1,3-bis(imidazol-1-ylmethyl)benzene; H4L = 2,6-di(2,4-dicarboxyphenyl)-4-(pyridine-4-yl)pyridine); Bp = 4,4′-bipyridine; BTC = 1,3,5-benzene tricarboxylate; H2LNA = 2,6-naphthalenedicarboxylic acid; H2L-NH2 = 2,2′-diamino[1,1′-biphenyl]-4,4′-dicarboxylic acid; CSMCRI-10 = Central Salt & Marine Chemicals Research Institute; BuPh3P = (4-bromobutyl)triphenylphosphonium bromide; SIPA = 5-sulfoisopthalic acid; ABPY = 4,4′-azopyridine; 5-CFIA = 5-(carboxyformamido)isophthalic acid; BDC = 1,4-benzenedicarboxylate; A = acid; B = base; (BINDIH4) = N,N′-bis(5-isophthalic acid)naphthalenediimide; DATRZ = 3,5-diamino-1,2,4-triazole; pypz = bis[3,5-dimethyl-4-(4′-pyridyl)pyrazol-1-yl] methane; PBA = 5-(4-pyridin-3-yl-benzoylamino)isophthalic acid; H2NDTz = 2,6-naphthaleneditetrazole; H2NDPhTz = 2,6-bis(4-(1H-tetrazol-5-yl)phenyl)naphthalene; Arg = Arginine.