Table 7. Overview of the Accuracy of SAFT-γ Mie in the Calculation of Vapor Pressures P_vap(T), Densities ρ(T,P), and Vaporization Enthalpies Δh_vap(T) for Pure Lactones, Where N^D_s,p Is the Number of Experimental Data Points Used in the Parameter Estimation, and N^D,total_s,p Is the Number of Experimental Data Used to Calculate %AAD_sp and AAD_sp for System s and Property p.

compound s	T/K range	NDs,p	ND,totals,p	%AADsPvap(T)	AADsPvap (T)/Pa	figure	ref
oxolan-2-one	289–478	11	26	5.063	1796	2(a,b), 3(a,b)	(69,70)
oxan-2-one	278–353	9	51	44.58	46.23	2(a,b)	(71)
oxepan-2-one	283–353	9	16	7.853	5.722	2(a,b)	(72)
5-methyloxolan-2-one	308–470	9	33	25.17	1929	3(a,b)	(58,73)
5-ethyloxolan-2-one	283–353	9	24	32.58	41.39	3(a,b)	(74)
5-propyloxolan-2-one	298–363	7	14	22.26	31.59	3(a,b)	(74)
5-butyloxolan-2-one	293–298	1	2	28.76	0.6564	3(a,b)	(75)
5-pentyloxolan-2-one	296–363	7	14	21.01	6.107	3(a,b)	(74)
5-hexyloxolan-2-one	298–365	10	23	17.58	2.262	3(a,b)	(74)
6-methyloxan-2-one	283–353	10	29	10.09	4.150	4(a,b)	(71)
6-propyloxan-2-one	288–353	10	18	1.663	0.3405	4(a,b)	(71)
6-butyloxan-2-one	293–348	7	12	8.045	0.6939	4(a,b)	(71)
6-pentyloxan-2-one	309–358	10	23	30.63	3.206	4(a,b)	(71)

compound s	T/K range	P/MPa range	NDs,p	ND,totals,p	%AADs ρ(T, P)	AADs ρ(T,P)/(kg/m3)	figure	ref
oxolan-2-one	253–473	0.101–35.0	13	363	1.021	10.90	2(c), 3(c)	(76,77)
oxan-2-one	293–318	0.101–10.0	4	10	3.416	37.62	2(c)	(78),79
oxepan-2-one	293–323	0.100	3	7	4.834	51.40	2(c)	(80)
5-methyloxolan-2-one	293–453	0.186–0.983	14	72	1.257	11.92	3(c)	(73)
5-butyloxolan-2-one	273–293	0.101	0	2	1.838	18.09	3(c)	(81)
5-pentyloxolan-2-one	273–290	0.101	0	2	1.870	18.18	3(c)	(81)
5-hexyloxolan-2-one	273–294	0.101	0	2	2.109	20.22	3(c)	(81)
6-methyloxan-2-one	294	0.101	0	1	2.399	24.87	4(c)	(82)

compound s	T/K range	ΝDs,p	ND,totals,p	%AADs Δhvap(T)	AADs Δhvap (T)/(J/mol)	figure	ref
oxolan-2-one	289–329	10	14	2.462	1329	2(d), 3(d)	(69)
oxan-2-one	278–353	9	51	3.659	2095	2(d)	(71)
oxepan-2-one	283–353	9	16	0.7581	454.7	2(d)	(72)
5-methyloxolan-2-one	276–350	10	22	2.751	1453	3(d)	(74)
5-ethyloxolan-2-one	283–353	9	24	4.048	2273	3(d)	(74)
5-propyloxolan-2-one	298–363	7	14	2.349	1407	3(d)	(74)
5-butyloxolan-2-one	298–324	2	2	3.159	2054	3(d)	(75)
5-pentyloxolan-2-one	296–363	7	14	3.400	2291	3(d)	(74)
5-hexyloxolan-2-one	298–365	10	23	2.141	1546	3(d)	(74)
6-methyloxan-2-one	283–353	10	29	3.988	2388	4(d)	(71)
6-propyloxan-2-one	288–353	10	18	0.6015	392.0	4(d)	(71)
6-butyloxan-2-one	293–348	7	12	1.865	1281	4(d)	(71)
6-pentyloxan-2-one	309–358	10	23	3.458	2441	4(d)	(71)