Table 9. Overview of the of Accuracy SAFT-γ Mie in the Calculation of Azeotrope Compositions xazoxolan-2-one and Temperatures Taz, Bubble Temperatures Tbub, Dew Temperatures Tdew, Bubble Pressures Pbub, Solubilities xsat1, Densities ρ, and Molar Excess Enthalpies Δhmix for Mixtures of Lactones and Primary Alcohols, Where NDs,p Is the Number of Experimental Data Used in the the Parameter Estimation, and ND,totals,p Is the Number of Experimental Data Used to Calculate %AADsp and AADsp for System s and Property p.
| system s (1 + 2) | T/K range | P/MPa range | x1 range | NDs,p | Ntotals,p | %AADsxazoxolan-2-one | AADsxazoxolan-2-one | figure | ref |
|---|---|---|---|---|---|---|---|---|---|
| oxolan-2-one + pentan-1-ol | − | 0.00267 | − | 0 | 1 | 100.0 | 0.002 | 8(a) | (83) |
| oxolan-2-one + hexan-1-ol | − | 0.00267 | − | 0 | 1 | 67.48 | 0.083 | 8(a) | (83) |
| oxolan-2-one + heptan-1-ol | − | 0.00267 | − | 0 | 1 | 17.30 | 0.06800 | 8(a) | (83) |
| oxolan-2-one + octan-1-ol | − | 0.00267 | − | 0 | 1 | 6.716 | 0.04365 | 8(a) | (83) |
| oxolan-2-one + nonan-1-ol | − | 0.00267 | − | 0 | 1 | 1.698 | 0.01444 | 8(a) | (83) |
| oxolan-2-one + decan-1-ol | − | 0.00267–0.101 | − | 0 | 2 | 12.03 | 0.1173 | 8(a) | (83) |
| oxolan-2-one + undecan-1-ol | − | 0.101 | − | 0 | 1 | 11.38 | 0.113 | 8(a) | (83) |
| system s (1 + 2) | T/K range | P/MPa range | x1 range | NDs,p | Ntotals,p | %AADsTaz | AADsTaz/K | figure | ref |
|---|---|---|---|---|---|---|---|---|---|
| oxolan-2-one + pentan-1-ol | − | 0.00267 | − | 0 | 1 | 0.1874 | 0.6167 | 8(b) | (83) |
| oxolan-2-one + hexan-1-ol | − | 0.00267 | − | 0 | 1 | 0.4756 | 1.632 | 8(b) | (83) |
| oxolan-2-one + heptan-1-ol | − | 0.00267 | − | 0 | 1 | 0.3069 | 1.090 | 8(b) | (83) |
| oxolan-2-one + decan-1-ol | − | 0.00267–0.101 | − | 0 | 2 | 0.5516 | 2.357 | 8(b) | (83) |
| oxolan-2-one + undecan-1-ol | − | 0.101 | − | 0 | 1 | 0.0879 | 0.4210 | 8(b) | (83) |
| system s (1 + 2) | T/K range | P/MPa range | x1 range | NDs,p | Ntotals,p | %AADsTbub | AADsTbub/K | figure | ref |
|---|---|---|---|---|---|---|---|---|---|
| oxolan-2-one +1,4-butanediol | − | 0.030–0.070 | 0.00–1.00 | 18 | 36 | 0.8126 | 3.792 | − | (94) |
| 5-methyloxolan-2-one + methanol | − | 0.101 | 0.00–0.82 | 18 | 18 | 0.3492 | 1.269 | 7(a) | (95) |
| 5-methyloxolan-2-one + ethanol | − | 0.101 | 0.00–0.82 | 12 | 35 | 0.1422 | 0.5184 | 7(a) | (95) |
| system s (1 + 2) | T/K range | P/MPa range | x1 range | NDs,p | Ntotals,p | %AADsTdew | AADsTdew/K | figure | ref |
|---|---|---|---|---|---|---|---|---|---|
| oxolan-2-one +1,4-butanediol | − | 0.030–0.070 | 0.00–1.00 | 18 | 36 | 0.8611 | 3.998 | − | (94) |
| 5-methyloxolan-2-one + methanol | − | 0.101 | 0.00–0.03 | 6 | 18 | 0.3080 | 1.112 | 7(a) | (95) |
| 5-methyloxolan-2-one + ethanol | − | 0.101 | 0.00–0.05 | 12 | 35 | 0.3411 | 1.261 | 7(a) | (95) |
| system s (1 + 2) | T/K range | P/MPa range | x1 range | NDs,p | Ntotals,p | %AADsPbub | AADsPbub/Pa | figure | ref |
|---|---|---|---|---|---|---|---|---|---|
| oxolan-2-one +1,4-butanediol | 373–423 | − | 0.00–1.00 | 32 | 32 | 14.73 | 795.3 | − | (92,93) |
| system s (1 + 2) | T/K range | P/MPa range | x1 range | NDs,p | Ntotals,p | %AADsxsat1 | AADsxsat1 | figure | ref |
|---|---|---|---|---|---|---|---|---|---|
| oxepan-2-one in methanol | 204–272 | 0.101 | − | 21 | 22 | 1.702 | 0.007757 | 7(b) | (66) |
| oxepan-2-one in propanol | 204–272 | 0.101 | − | 19 | 20 | 4.388 | 0.01220 | 7(b) | (66) |
| system s (1 + 2) | T/K range | P/MPa range | x1 range | NDs,p | Ntotals,p | %AADs ρ | AADs ρ/(kg/m3) | figure | ref |
|---|---|---|---|---|---|---|---|---|---|
| oxolan-2-one + methanol | 298 | 0.101 | 0.00–1.00 | 11 | 11 | 0.5953 | 6.281 | 7(c) | (97) |
| oxolan-2-one + ethanol | 298 | 0.101 | 0.00–1.00 | 11 | 11 | 0.9588 | 8.877 | 7(c) | (97) |
| oxolan-2-one + butan-1-ol | 293–303 | 0.101 | 0.00–1.00 | 24 | 59 | 1.209 | 11.29 | 7(c) | (97,98) |
| oxolan-2-one + octan-1-ol | 298 | 0.101 | 0.00–1.00 | 0 | 11 | 3.438 | 31.92 | 7(c) | (97) |
| oxolan-2-one + 2-methyl-1-propanol | 303 | 0.101 | 0.00–1.00 | 10 | 10 | 1.367 | 12.39 | − | (96) |
| oxolan-2-one + 3-methyl-1-butanol | 303 | 0.101 | 0.00–1.00 | 10 | 10 | 1.384 | 12.59 | − | (96) |
| system s (1 + 2) | T/K range | P/MPa range | x1 range | NDs,p | Ntotals,p | %AADs Δhmix | AADs Δhmix/(J/mol) | figure | ref |
|---|---|---|---|---|---|---|---|---|---|
| oxolan-2-one + methanol | 298 | 0.101 | 0.89–0.99 | 5 | 5 | 4.694 | 12.56 | 7(d) | (100) |
| oxolan-2-one + hexan-1-ol | 298 | 0.101 | 0.12–0.94 | 12 | 12 | 7.594 | 113.3 | 7(d) | (99) |
| oxolan-2-one + heptan-1-ol | 298 | 0.101 | 0.15–0.95 | 12 | 12 | 4.447 | 74.57 | 7(d) | (99) |
| oxolan-2-one + octan-1-ol | 298 | 0.101 | 0.17–0.95 | 0 | 12 | 9.077 | 172.5 | 7(d) | (99) |
| oxolan-2-one + decan-1-ol | 298 | 0.101 | 0.21–0.96 | 0 | 12 | 11.06 | 206.2 | 7(d) | (99) |