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. 2024 Feb 19;14(9):5941–5958. doi: 10.1039/d4ra00290c

Table 3. Textural properties of the Li/MCM-41 catalystsa.

Catalyst Basicity (mmol g−1) Basic strength (H_) GC yield (%)
MCM-41 1.11 H_ ≤ 7.2 2.96
2%Li/MCM-41 1.45 7.2 ≤ H_ ≤ 9.8 17.24
3%Li/MCM-41 2.03 7.2 ≤ H_ ≤ 9.8 22.25
4%Li/MCM-41 2.49 7.2 ≤ H_ ≤ 9.8 29.30
5%Li/MCM-41 4.70 9.8 ≤ H_ ≤ 15 58.77
6%Li/MCM-41 5.05 9.8 ≤ H_ ≤15 47.27
a

Reaction conditions: catalyst loading of 5 wt%, DMC to enriched glycerol molar ratio of 4 : 1, reaction temperature of 85 °C, and reaction time of 150 min.