Table 4. Actual and predicted values for the response surface analysis of GC synthesis over the 5%Li/MCM-41 catalyst.
| Standard run | Catalyst loading (wt%) | DMC: enriched glycerol molar ratio | Reaction temperature (°C) | Reaction time (min) | GC yield (%) | |||||
|---|---|---|---|---|---|---|---|---|---|---|
| Coded | Real | Coded | Real | Coded | Real | Coded | Real | Observed | Predicted | |
| 1 | −1 | 3 | +1 | 4 : 1 | −1 | 75 | −1 | 90 | 36.77 | 36.71 |
| 2 | +1 | 5 | +1 | 4 : 1 | −1 | 75 | −1 | 90 | 43.62 | 44.25 |
| 3 | +1 | 5 | −1 | 2 : 1 | −1 | 75 | +1 | 150 | 44.15 | 43.08 |
| 4 | +1 | 5 | −1 | 2 : 1 | −1 | 75 | −1 | 90 | 42.08 | 43.00 |
| 5 | 0 | 4 | 0 | 3 : 1 | 0 | 80 | +2 | 180 | 53.75 | 54.28 |
| 6 | +1 | 5 | −1 | 2 : 1 | +1 | 85 | −1 | 90 | 37.78 | 38.72 |
| 7 | 0 | 4 | 0 | 3 : 1 | 0 | 80 | 0 | 120 | 54.90 | 55.31 |
| 8 | +1 | 5 | +1 | 4 : 1 | −1 | 75 | +1 | 150 | 46.82 | 46.92 |
| 9 | −1 | 3 | −1 | 2 : 1 | −1 | 75 | −1 | 90 | 46.34 | 44.32 |
| 10 | −1 | 3 | −1 | 2 : 1 | +1 | 85 | −1 | 90 | 41.09 | 40.53 |
| 11 | 0 | 4 | 0 | 3 : 1 | +2 | 90 | 0 | 120 | 48.77 | 47.72 |
| 12 | 0 | 4 | 0 | 3 : 1 | 0 | 80 | −2 | 60 | 48.16 | 47.65 |
| 13 | −1 | 3 | −1 | 2 : 1 | −1 | 75 | +1 | 150 | 45.94 | 45.82 |
| 14 | −1 | 3 | +1 | 4 : 1 | −1 | 75 | +1 | 150 | 41.31 | 40.81 |
| 15 | 0 | 4 | 0 | 3 : 1 | 0 | 80 | 0 | 120 | 55.64 | 55.31 |
| 16 | 0 | 4 | 0 | 3 : 1 | 0 | 80 | 0 | 120 | 55.75 | 55.31 |
| 17 | 0 | 4 | 0 | 3 : 1 | 0 | 80 | 0 | 120 | 56.46 | 55.31 |
| 18 | +1 | 5 | +1 | 4 : 1 | +1 | 85 | +1 | 150 | 57.18 | 59.65 |
| 19 | 0 | 4 | 0 | 3 : 1 | −2 | 70 | 0 | 120 | 37.72 | 38.78 |
| 20 | −1 | 3 | +1 | 4 : 1 | +1 | 85 | +1 | 150 | 55.40 | 54.03 |
| 21 | +1 | 5 | +1 | 4 : 1 | +1 | 85 | −1 | 90 | 54.86 | 54.52 |
| 22 | +2 | 6 | 0 | 3 : 1 | 0 | 80 | 0 | 120 | 51.33 | 49.70 |
| 23 | 0 | 4 | +2 | 5 : 1 | 0 | 80 | 0 | 120 | 46.25 | 45.02 |
| 24 | 0 | 4 | 0 | 3 : 1 | 0 | 80 | 0 | 120 | 55.61 | 55.31 |
| 25 | +1 | 5 | −1 | 2 : 1 | +1 | 85 | +1 | 150 | 41.64 | 41.25 |
| 26 | −2 | 2 | 0 | 3 : 1 | 0 | 80 | 0 | 120 | 43.76 | 45.40 |
| 27 | −1 | 3 | +1 | 4 : 1 | +1 | 85 | −1 | 90 | 45.96 | 47.48 |
| 28 | −1 | 3 | −1 | 2 : 1 | +1 | 85 | +1 | 150 | 44.67 | 44.49 |
| 29 | 0 | 4 | 0 | 3 : 1 | 0 | 80 | 0 | 120 | 53.51 | 55.31 |
| 30 | 0 | 4 | −2 | 1 : 1 | 0 | 80 | 0 | 120 | 32.99 | 34.23 |