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. 2024 Feb 19;14(9):5941–5958. doi: 10.1039/d4ra00290c

Table 4. Actual and predicted values for the response surface analysis of GC synthesis over the 5%Li/MCM-41 catalyst.

Standard run Catalyst loading (wt%) DMC: enriched glycerol molar ratio Reaction temperature (°C) Reaction time (min) GC yield (%)
Coded Real Coded Real Coded Real Coded Real Observed Predicted
1 −1 3 +1 4 : 1 −1 75 −1 90 36.77 36.71
2 +1 5 +1 4 : 1 −1 75 −1 90 43.62 44.25
3 +1 5 −1 2 : 1 −1 75 +1 150 44.15 43.08
4 +1 5 −1 2 : 1 −1 75 −1 90 42.08 43.00
5 0 4 0 3 : 1 0 80 +2 180 53.75 54.28
6 +1 5 −1 2 : 1 +1 85 −1 90 37.78 38.72
7 0 4 0 3 : 1 0 80 0 120 54.90 55.31
8 +1 5 +1 4 : 1 −1 75 +1 150 46.82 46.92
9 −1 3 −1 2 : 1 −1 75 −1 90 46.34 44.32
10 −1 3 −1 2 : 1 +1 85 −1 90 41.09 40.53
11 0 4 0 3 : 1 +2 90 0 120 48.77 47.72
12 0 4 0 3 : 1 0 80 −2 60 48.16 47.65
13 −1 3 −1 2 : 1 −1 75 +1 150 45.94 45.82
14 −1 3 +1 4 : 1 −1 75 +1 150 41.31 40.81
15 0 4 0 3 : 1 0 80 0 120 55.64 55.31
16 0 4 0 3 : 1 0 80 0 120 55.75 55.31
17 0 4 0 3 : 1 0 80 0 120 56.46 55.31
18 +1 5 +1 4 : 1 +1 85 +1 150 57.18 59.65
19 0 4 0 3 : 1 −2 70 0 120 37.72 38.78
20 −1 3 +1 4 : 1 +1 85 +1 150 55.40 54.03
21 +1 5 +1 4 : 1 +1 85 −1 90 54.86 54.52
22 +2 6 0 3 : 1 0 80 0 120 51.33 49.70
23 0 4 +2 5 : 1 0 80 0 120 46.25 45.02
24 0 4 0 3 : 1 0 80 0 120 55.61 55.31
25 +1 5 −1 2 : 1 +1 85 +1 150 41.64 41.25
26 −2 2 0 3 : 1 0 80 0 120 43.76 45.40
27 −1 3 +1 4 : 1 +1 85 −1 90 45.96 47.48
28 −1 3 −1 2 : 1 +1 85 +1 150 44.67 44.49
29 0 4 0 3 : 1 0 80 0 120 53.51 55.31
30 0 4 −2 1 : 1 0 80 0 120 32.99 34.23