Table 6. Reported carbonation studies using different rock minerals.
Main mineral | Concentration (g L−1) | Temperature (°C) | Pressure | Volume of reaction (L) | CO2 intake | % leaching | Carbonation yield and CO2 fixed | Residence time | Ref. |
---|---|---|---|---|---|---|---|---|---|
Serpentine | 150 | Room temperature | 8 atm | ∼6.2 | 14–18% CO2 | 17.3 (Mg) | 17.9%, 0.215 g CO2 per g solid | 6 h | 48 |
Olivine | 100 | 185 | 6.5 MPa | 0.045 | 18.2% CO2 | 34 (Mg) | 74.8%, N.Q. | Up to 6 h | 63 |
Serpentine/lizardite | 50–150 | 22 | 10.5 atm | 0.3 (reactor size) | 18.2% CO2 | N.Q. | 30%, 0.55 g CO2 per g solid | 2.25 h | 61 |
Lizardite | 150 | 100–150 | 20–150 | ∼0.3 | 100% CO2 | N.Q. | 30%,a N.Q. | Up to 6 h | 64 |
Lizardite | 150 | Room temperature | 0.4–1.6 bar | ∼5.0 | 14–18% CO2 | ∼15.8% | 33.3%, 0.08 g CO2 per g solid | 6 h | 60 |
Olivine | ∼200 | Up to 190 | 40–100 bar | 0.01 | 100% CO2 | N.Q. | 100%, N.Q. | Up to 6 h | 59 |
Rich Mg-bearing silicates | 100 | 185 | 20.7–38.6 bar | 0.6 (reactor size) | 100% CO2 | N.Q. | 71%, N.Q. | 5 h | 57 |
Olivine | 150 | Room temperature (mineral dissolution) – 35–40 °C (carbonation) | 3 bar (dissolution) – ambient pressure (carbonation) | 0.17 | 1 g per L HCO3− | 0.4% (Mg) | 6.9%, N.Q. | 5 days (mineral dissolution) + 12 h (carbonation) | This study (not optimized) |
Wollastonite | 2 | Room temperature | 2 bar | 2 | 100% CO2 | N.Q. | N.Q., 0.14 g CO2 per g solid | 22 days | 68 |
MgCO3 yield.