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. Author manuscript; available in PMC: 2024 Feb 21.
Published in final edited form as: Anal Chem. 2018 Aug 6;90(16):10049–10055. doi: 10.1021/acs.analchem.8b02750

Table 1.

Electrode Characteristics Determined by CV Analysisa

Edeposit (V) n ECSA (μm2) ρ ΔE1/2 (mV) ΔE1/4 (mV) ΔE3/4 (mV)
bare CFE 14 277 ± 11b 219 ± 9b
−0.3 10 55.0 ± 14.1 1.98 ± 0.51 −80 ± 18 193 ± 10** 155 ± 14**
−0.4 14 94.4 ± 14.8 3.41 ± 0.53 −74 ± 15 207 ± 6** 132 ± 17**
−0.5 12 101.1 ± 23.0 3.65 ± 0.83 −105 ± 19 175 ± 14** 147 ± 20*
−0.6 10 133.0 ± 28.9 4.80 ± 1.04 −79 ± 27 170 ± 12** 144 ± 12
a

ECSA and ρ are from H2SO4 CVs, and ΔE1/2, ΔE1/4, ΔE3/4 are from dopamine CVs. Significance of kinetic enhancement was assessed using paired Mann-Whitney test.

**

p < 0.01,

*

p < 0.05.

b

Bare CFE kinetic data corresponds to unmodified electrodes from the −0.4 V group.