Primary crops (available studies) | Crop groups | Crops | Applications | Sampling (DAT) a | Comment/source |
Fruit crops | Tomatoes b | Foliar, 1 × 167–173 g a.s./ha | 0, 12 and 105 | EFSA (2017) [quizalofop‐P‐ethyl] | |
Root crops | Sugar beets b | Foliar, 1 × 280 g a.s./ha | 31, 60 and 90 | EFSA (2017) [quizalofop‐P‐ethyl] | |
Sugar beets c | Foliar, 1 × 6 g a.s./ha | 28 | EFSA (2017) [quizalofop‐P‐ethyl] | ||
Sugar beets | Foliar, 2 × 200 g a.s./ha | 98–114 DALA | Quinoxaline‐labelled propaquizafop EFSA (2017) | ||
Potatoes c | Foliar, 1 × 6 g a.s./ha | 14 | EFSA (2017) [quizalofop‐P‐ethyl] | ||
Potatoes | Foliar, 2 × 105–545 g a.s./ha | 40, 62 | Radiolabelled active substance: phenyl‐14C‐quizalofop‐P‐tefuryl and quinoxaline‐14C‐quizalofop‐P‐tefuryl (EFSA, 2017) [quizalofop‐P‐tefuryl] | ||
Sugar beets d | Foliar, 1 × 316 g a.s./ha | 31 | EFSA (2017) [quizalofop‐P‐ethyl] | ||
Leafy crops | Lettuces | Foliar, 1 × 200 g a.s./ha | 77 | Hydroquinone and chlorophenyl‐labelled propaquizafop (EFSA, 2017) | |
Lettuces | Foliar, 2 × 1000 g a.s./ha | 77 | Hydroquinone‐labelled propaquizafop (EFSA, 2017) | ||
Pulses/oilseeds | Cotton | Foliar, 2 × 209–580 g a.s./ha | 180 | Radiolabelled active substance: phenyl‐14C‐quizalofop‐P‐tefuryl and quinoxaline‐14C‐quizalofop‐P‐tefuryl (EFSA, 2017) [quizalofop‐P‐tefuryl] | |
Foliar, 1 × 2.78 kg a.s./ha | 10 | ||||
Cotton e | Foliar, 1 × 260 g a.s./ha | 0, 7, 21 and 42 | EFSA (2017); [quizalofop‐P‐ethyl] | ||
Cotton | Onto leaf, 180 g a.s./ha | 0–51 | Hydroquinone and chlorophenyl‐labelled propaquizafop (EFSA, 2017) | ||
Foliar, 1 × 200 g a.s./ha | 0, 6, 12, 22 | Quinoxaline‐labelled propaquizafop (EFSA, 2017) | |||
Foliar, 1 × 214 g a.s./ha | 0, 15, 22 DALA | Hydroquinone‐labelled propaquizafop (EFSA, 2017) | |||
Soyabeans | Onto leaf, 1 × 100 g a.s./ha | 0 to 28 | Hydroquinone‐labelled propaquizafop (EFSA, 2017) | ||
Foliar, 1 × 190 g a.s./ha | 0, 7, 14 | ||||
Foliar, 1 × 268–298 g a.s./ha | 66, 70 | ||||
Soyabeans | Foliar, 1 × 200 g a.s./ha | 8, 15 | Quinoxaline‐labelled propaquizafop (EFSA, 2017) | ||
Foliar, 1 × 280 g a.s./ha | 66, 100 DALA | ||||
Soyabeans | Foliar, 1 × 100–400 g a.s./ha | 14, 34 and 61 | Radiolabelled active substance: phenyl‐14C‐quizalofop‐P‐tefuryl (EFSA, 2017) [quizalofop‐P‐tefuryl] | ||
Foliar, 2 × 290–580 g a.s./ha | 84 | Radiolabelled active substance: phenyl‐14C‐quizalofop‐P‐tefuryl and quinoxaline‐14C‐quizalofop‐P‐tefuryl (Finland, 2007; EFSA, 2017) [quizalofop‐P‐tefuryl] | |||
Foliar, 2 × 2.2 kg a.s./ha | 10 | ||||
Foliar, 2 × 120–480 g a.s./ha | 6, 18 and 49 | ||||
Soya beans e | Foliar, 1 × 273–287 g a.s./ha | 0, 7, 21 and 42 | EFSA (2017) [quizalofop‐P‐ethyl] | ||
Soya beans f | Foliar, 1 × 280 g a.s./ha | 0, 7, 14, 29 and 63 | |||
Soya beans g |
Foliar, 1 × 340 g a.s./ha (R/S); 1 × 160 g a.s./ha (R + S) |
1, 14 and 105 | |||
Cereals | GM maize b (aad‐1 gene) | 1 × 98 g a.s./ha | 48 (forage); 72 (grain, cobs, stover/fodder) | EFSA (2018b) for a study in GM maize [quizalofop‐P‐ethyl] | |
Rotational crops (available studies) | Crop groups | Crops | Applications | PBI (DAT) | Comment/Source |
Root/tuber crops | Sugar beets e | Bare soil, 308 g a.s./ha | 30, 60 | EFSA (2017) [quizalofop‐P‐ethyl] | |
Sugar beets | Soybeans, 2 × 280 g a.s./ha | 30, 120, 270 | Quinoxaline‐labelled propaquizafop EFSA (2017) | ||
Turnips | Bare soil, 250 g a.s./ha | 30, 120, 240, 540 | Radiolabelled active substance: quinoxaline‐14C‐quizalofop‐P‐tefuryl. The crops planted 1 month after the treatment (30 DAT) were lost because of crop failure [quizalofop‐P‐tefuryl] EFSA (2017) | ||
Leafy crops | Lettuces e | Bare soil, 308 g a.s./ha | 30, 60 | [quizalofop‐P‐ethyl] EFSA (2017) | |
Lettuces | Bare soil, 250 g a.s./ha | 30, 120, 240, 540 | Radiolabelled active substance: quinoxaline‐14C‐quizalofop‐P‐tefuryl. The crops planted 1 month after the treatment (30 DAT) were lost because of crop failure [quizalofop‐P‐tefuryl] EFSA (2017) | ||
Spinaches | Soybeans, 2 × 280 g a.s./ha | 30, 120, 270 | Quinoxaline‐labelled propaquizafop (EFSA, 2017) | ||
Pulses and oilseeds | Cotton seeds e Peanuts e | Bare soil, 308 g a.s./ha | 30, 60 | [quizalofop‐P‐ethyl] EFSA (2017) | |
Cereal (small grain) | Wheat e | Bare soil, 308 g a.s./ha | 30, 60 | [quizalofop‐P‐ethyl] EFSA (2017) | |
Wheat | Bare soil, 250 g a.s./ha | 30, 120, 240, 540 | Radiolabelled active substance: quinoxaline‐14C‐quizalofop‐P‐tefuryl. The crops planted 1 month after the treatment (30 DAT) were lost because of crop failure [quizalofop‐P‐tefuryl] EFSA (2017) | ||
Wheat | Soybeans, 2 × 280 g a.s./ha | 30, 120, 270 | Quinoxaline‐labelled propaquizafop EFSA (2017) | ||
Processed commodities (hydrolysis study) | Conditions | Stable? | Comment/Source | ||
Pasteurisation (20 min, 90°C, pH 4) | Yes |
Standard hydrolysis studies performed with quizalofop in the framework of the MRL review for quizalofop‐P‐tefuryl and expected to cover all three ester variants (EFSA, 2017) and with quizalofop‐P‐ethyl (EFSA, 2021) No study available propaquizafop, but the available studies cover all three ester variants (EFSA, 2021) |
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Abbreviation: PBI, plant‐back interval.
DAT: days after treatment; DALA: days after the last application.
Phenyl‐ and quinoxaline‐labelled quizalofop‐P‐ethyl (R‐enantiomer).
Phenyl‐labelled quizalofop‐ethyl (Racemate (R/S)). Study results used for information only considering the low application rate.
Phenyl‐labelled quizalofop‐P‐ethyl (R‐enantiomer). Residues analysed in foliage only.
Phenyl‐ and quinoxaline‐labelled quizalofop‐ethyl (racemate (R/S)).
Phenyl‐ and quinoxaline‐labelled quizalofop‐ethyl (racemate (R/S) and R‐enantiomer).
Quinoxaline‐labelled quizalofop‐ethyl (racemate (R/S) and R‐ and S‐enantiomer).