Table 2.
13C NMR data of 1 − 4 in CDCl3
| No | 1a | 2a | 3b | 4b |
|---|---|---|---|---|
| 2 | 92.3, C | 88.1, C | 93.0, C | 89.4, C |
| 3 | 190.8, C | 194.6, C | 190.8, C | 194.2, C |
| 3a | 104.1, C | 105.3, C | 105.0, C | 105.9, C |
| 4 | 159.6, C | 159.3, C | 158.3, C | 158.0, C |
| 5 | 93.9, CH | 93.9, CH | 90.1, CH | 89.9, CH |
| 6 | 170.7, C | 171.0, C | 165.0, C | 165.2, C |
| 7 | 89.0, CH | 89.1, CH | 97.8, C | 97.9, C |
| 7a | 175.9, C | 175.9, C | 169.3, C | 169.3, C |
| 2' | 168.7, C | 169.1, C | 168.1, C | 168.5, C |
| 3' | 104.0, CH | 104.9, CH | 104.2, CH | 105.1, CH |
| 4' | 195.7, C | 195.9, C | 195.4, C | 195.6, C |
| 5' | 46.1, CH2 | 47.2, CH2 | 46.1, CH2 | 47.2, CH2 |
| 6' | 74.8, C | 74.5, C | 74.7, C | 74.7, C |
| 4-OCH3 | 56.3, CH3 | 56.4, CH3 | 56.6, CH3 | 56.6, CH3 |
| 6-OCH3 | 56.3, CH3 | 56.4, CH3 | 57.2, CH3 | 57.2, CH3 |
| 2'-OCH3 | 56.8, CH3 | 56.8, CH3 | 56.9, CH3 | 56.9, CH3 |
| 6'-CH3 | 23.3, CH3 | 23.7, CH3 | 23.3, CH3 | 23.9, CH3 |
a13C NMR tested with 100 MHz.
b13C NMR tested with 150 MHz.