Table 3.
1H NMR data of 10 − 12, 14 − 15 (400 MHz, J in Hz)
No | 10a | 11a | 12a | 14b | 15b |
---|---|---|---|---|---|
5 | 6.21, s | 5.96, d (1.7) | 5.99, d (2.0) | ||
7 | 6.41, s | 6.16, d (1.7) | 6.28, d (2.0) | ||
2' | 3.90, dd (11.8, 4.8) | ||||
3' | 5.62, s | 5.62, s | 5.64, s | 2.30, m | 6.08, dd (10.1, 2.1) |
1.86, m | |||||
4’ | 1.83, m | 7.14, ddd (10.1, 5.8, 2.2) | |||
1.39, m | |||||
5' | 2.90, dd (15.4, 13.2) | 2.89, dd (16.4, 13.4) | 2.90, dd (15.4, 13.2) | 2.00, m | 3.03, ddt (19.2, 11.0, 2.6) |
2.42, dd (15.4, 3.5) | 2.42, dd (16.4, 4.4) | 2.43, dd (15.5, 3.2) | 1.50, m | 2.47, dt (19.3, 5.7) | |
6' | 2.83, m | 2.78, m | 2.85, m | 1.92, m | 2.75, m |
4-OCH3 | 3.87, s | 4.05, s | 4.02, s | 3.86, s | 3.85, s |
6-OCH3 | 3.85, s | 3.87, s | |||
2'-OCH3 | 3.70, s | 3.70, s | 3.71, s | ||
6'-CH3 | 0.91, d (6.4) | 0.93, d (6.5) | 0.93, d (6.2) | 0.81, d (6.4) | 1.01, d (6.7) |
aData were recorded in CD3OD.
bData were recorded in CDCl3.