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. 2024 Jan 19;6(2):853–861. doi: 10.1021/acsaelm.3c01390

Table 2. EXAFS Fitting Results for (Al0.75Sc25)N, (Al0.70Sc30)N, ScN Powder, (Al0.75Y25)N, and Y Foila,b.

sample path CN S02 R (Å) σ22) ΔE0 (eV)
Al0.75Sc0.25N Sc–N 4 0.81 ± 0.27 2.11 ± 0.03 0.005 ± 0.005 1.0 ± 3.4
Al0.70Sc0.30N Sc–N 4 0.69 ± 0.17 2.12 ± 0.02 0.004 ± 0.004 –0.5 ± 2.6
ScN Sc–N 6 0.34 ± 0.05 2.27 ± 0.03 0.001 ± 0.003 2.4 ± 3.9
Sc–Sc 12 0.34 ± 0.05 3.19 ± 0.01 0.001 ± 0.001 –3.0 ± 1.5
Al0.75Y0.25N Y–N 3.7 ± 1.3 0.82 2.24 ± 0.03 0.000 ± 0.006 –4.2 ± 3.3
Y foil Y–Y 12 0.82 ± 0.16 3.61 ± 0.01 0.014 ± 0.002 –0.8 ± 0.9
AlN25 Al–N 4   1.92 ± 0.01    
a

CN is the coordination number (i.e., number of nearest neighbors at distance R per absorbing atom); R is the first near neighbor distance; σ2 is the mean squared relative bond disorder (also referred to as the EXAFS Debye–Waller factor); ΔE0 is the correction in the photoelectron energy origin, and S02 is the amplitude reduction factor.

b

Reference to structural AlN data from the literature.25