Table 2. EXAFS Fitting Results for (Al0.75Sc25)N, (Al0.70Sc30)N, ScN Powder, (Al0.75Y25)N, and Y Foila,b.
| sample | path | CN | S02 | R (Å) | σ2 (Å2) | ΔE0 (eV) |
|---|---|---|---|---|---|---|
| Al0.75Sc0.25N | Sc–N | 4 | 0.81 ± 0.27 | 2.11 ± 0.03 | 0.005 ± 0.005 | 1.0 ± 3.4 |
| Al0.70Sc0.30N | Sc–N | 4 | 0.69 ± 0.17 | 2.12 ± 0.02 | 0.004 ± 0.004 | –0.5 ± 2.6 |
| ScN | Sc–N | 6 | 0.34 ± 0.05 | 2.27 ± 0.03 | 0.001 ± 0.003 | 2.4 ± 3.9 |
| Sc–Sc | 12 | 0.34 ± 0.05 | 3.19 ± 0.01 | 0.001 ± 0.001 | –3.0 ± 1.5 | |
| Al0.75Y0.25N | Y–N | 3.7 ± 1.3 | 0.82 | 2.24 ± 0.03 | 0.000 ± 0.006 | –4.2 ± 3.3 |
| Y foil | Y–Y | 12 | 0.82 ± 0.16 | 3.61 ± 0.01 | 0.014 ± 0.002 | –0.8 ± 0.9 |
| AlN25 | Al–N | 4 | 1.92 ± 0.01 |
CN is the coordination number (i.e., number of nearest neighbors at distance R per absorbing atom); R is the first near neighbor distance; σ2 is the mean squared relative bond disorder (also referred to as the EXAFS Debye–Waller factor); ΔE0 is the correction in the photoelectron energy origin, and S02 is the amplitude reduction factor.
Reference to structural AlN data from the literature.25