Table 3 |.

Reaction Scope with Additional Donors. Reaction Conditions: Donor 1 (0.06 mmol), Acceptor (0.12 mmol), (PhO)₃PAuCl/AgNTf₂ (0.006 mmol), HNTf₂ (0.012 mmol), PhCF₃ (0.08 M), Drierite, 0 °C.

^aStarting from the donor with a 15/1 α/β ratio.

^b−20 °C.

^cStarting from the donor with a 22/1 α/β ratio.