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. 2024 Feb 15;14(5):3248–3265. doi: 10.1021/acscatal.3c05072

Table 3. Effects of Isotopic Substitution on Rate Constants of H2O2 and H2O Formation on 2 and 25 nm Au Nanoparticles Supported on TiO2 (200 kPa H2 or 200 kPa D2, 60 kPa O2, 278 K).

reaction Au nanoparticles
  2 nm 25 nm
H2 + O2 → H2O2 1.5 ± 0.1 1.6 ± 0.1
H2 + 1/2O2 → H2O 1.5 ± 0.3 1.5 ± 0.3