Table 3. Effects of Isotopic Substitution on Rate Constants of H2O2 and H2O Formation on 2 and 25 nm Au Nanoparticles Supported on TiO2 (200 kPa H2 or 200 kPa D2, 60 kPa O2, 278 K).
reaction | Au nanoparticles |
|
---|---|---|
2 nm | 25 nm | |
H2 + O2 → H2O2 | 1.5 ± 0.1 | 1.6 ± 0.1 |
H2 + 1/2O2 → H2O | 1.5 ± 0.3 | 1.5 ± 0.3 |