Synthesis and crystal structures of bis­[1-oxopyridin-2-olato(1−)]bis­(penta­fluoro­phen­yl)silicon(IV)–tetra­hydro­furan–pentane (2/1/1), bis­[1-oxopyridin-2-olato(1−)]bis­(p-tol­yl)silicon(IV), and dimesitylbis[1-oxopyridin-2-olato(1−)]silicon(IV)

. 2024 Feb 20;80(Pt 3):318–324. doi: 10.1107/S2056989024001543

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Si1	0.01361 (12)	0.01244 (12)	0.01899 (14)	−0.00038 (9)	0.00070 (10)	0.00039 (9)
O1	0.0211 (4)	0.0138 (3)	0.0178 (3)	0.0001 (3)	0.0015 (3)	0.0003 (3)
O2	0.0201 (3)	0.0138 (3)	0.0194 (3)	−0.0008 (3)	0.0020 (3)	0.0006 (3)
O3	0.0157 (3)	0.0129 (3)	0.0264 (4)	0.0001 (2)	0.0035 (3)	0.0010 (3)
O4	0.0140 (3)	0.0142 (3)	0.0232 (4)	0.0006 (2)	0.0031 (3)	0.0017 (3)
N1	0.0170 (4)	0.0152 (4)	0.0199 (4)	0.0008 (3)	0.0010 (3)	0.0011 (3)
C1	0.0167 (4)	0.0154 (4)	0.0197 (4)	0.0008 (3)	0.0010 (3)	0.0004 (3)
N2	0.0152 (4)	0.0161 (4)	0.0247 (5)	0.0002 (3)	0.0030 (3)	−0.0001 (3)
C6	0.0152 (4)	0.0139 (4)	0.0213 (4)	0.0010 (3)	0.0010 (3)	0.0006 (3)
N1'	0.0167 (4)	0.0154 (4)	0.0197 (4)	0.0008 (3)	0.0010 (3)	0.0004 (3)
C1'	0.0170 (4)	0.0152 (4)	0.0199 (4)	0.0008 (3)	0.0010 (3)	0.0011 (3)
N2'	0.0152 (4)	0.0139 (4)	0.0213 (4)	0.0010 (3)	0.0010 (3)	0.0006 (3)
C6'	0.0152 (4)	0.0161 (4)	0.0247 (5)	0.0002 (3)	0.0030 (3)	−0.0001 (3)
C2	0.0239 (5)	0.0188 (4)	0.0224 (5)	0.0009 (4)	0.0026 (4)	−0.0029 (4)
C3	0.0283 (6)	0.0269 (6)	0.0205 (5)	0.0035 (5)	0.0034 (4)	−0.0001 (4)
C4	0.0272 (6)	0.0237 (5)	0.0225 (5)	0.0021 (4)	0.0041 (4)	0.0045 (4)
C5	0.0226 (5)	0.0168 (4)	0.0227 (5)	0.0008 (4)	0.0020 (4)	0.0025 (4)
C7	0.0212 (5)	0.0145 (4)	0.0227 (5)	0.0008 (3)	0.0017 (4)	0.0009 (3)
C8	0.0228 (5)	0.0176 (5)	0.0334 (6)	0.0050 (4)	0.0031 (5)	−0.0002 (4)
C9	0.0215 (5)	0.0236 (5)	0.0466 (8)	0.0046 (4)	0.0103 (5)	−0.0014 (5)
C10	0.0187 (5)	0.0209 (5)	0.0390 (7)	−0.0003 (4)	0.0097 (5)	−0.0008 (5)
C11	0.0169 (4)	0.0134 (4)	0.0203 (5)	−0.0006 (3)	0.0023 (3)	0.0006 (3)
C12	0.0189 (4)	0.0148 (4)	0.0225 (5)	−0.0003 (3)	0.0033 (4)	−0.0002 (3)
F1	0.0220 (3)	0.0197 (3)	0.0281 (4)	0.0055 (3)	0.0010 (3)	0.0004 (3)
C13	0.0233 (5)	0.0162 (4)	0.0265 (5)	−0.0019 (4)	0.0072 (4)	−0.0028 (4)
F2	0.0306 (4)	0.0221 (3)	0.0392 (5)	0.0028 (3)	0.0114 (4)	−0.0084 (3)
C14	0.0280 (6)	0.0193 (5)	0.0212 (5)	−0.0071 (4)	0.0061 (4)	−0.0031 (4)
F3	0.0402 (5)	0.0288 (4)	0.0235 (4)	−0.0098 (3)	0.0091 (3)	−0.0074 (3)
C15	0.0243 (5)	0.0183 (4)	0.0194 (5)	−0.0047 (4)	−0.0005 (4)	0.0016 (4)
F4	0.0353 (4)	0.0258 (4)	0.0218 (4)	−0.0030 (3)	−0.0073 (3)	0.0025 (3)
C16	0.0185 (4)	0.0136 (4)	0.0213 (5)	−0.0014 (3)	0.0007 (4)	0.0007 (3)
F5	0.0221 (3)	0.0171 (3)	0.0266 (4)	0.0040 (2)	−0.0036 (3)	0.0004 (3)
C17	0.0155 (4)	0.0165 (4)	0.0233 (5)	0.0000 (3)	0.0033 (4)	−0.0009 (3)
C18	0.0184 (4)	0.0215 (5)	0.0267 (6)	−0.0011 (4)	0.0049 (4)	−0.0008 (4)
F6	0.0240 (4)	0.0300 (4)	0.0250 (4)	0.0003 (3)	0.0054 (3)	0.0031 (3)
C19	0.0229 (5)	0.0334 (7)	0.0362 (7)	−0.0040 (5)	0.0124 (5)	0.0005 (5)
F7	0.0343 (5)	0.0526 (6)	0.0457 (6)	−0.0077 (4)	0.0206 (4)	0.0073 (5)
C20	0.0165 (5)	0.0425 (8)	0.0457 (9)	−0.0052 (5)	0.0086 (5)	−0.0013 (7)
F8	0.0186 (4)	0.0766 (9)	0.0686 (8)	−0.0104 (5)	0.0126 (5)	0.0092 (7)
C21	0.0151 (5)	0.0373 (7)	0.0359 (7)	−0.0003 (5)	0.0012 (5)	0.0014 (6)
F9	0.0162 (4)	0.0625 (7)	0.0466 (6)	−0.0005 (4)	−0.0046 (4)	0.0081 (5)
C22	0.0148 (4)	0.0221 (5)	0.0274 (6)	−0.0001 (4)	0.0022 (4)	−0.0001 (4)
F10	0.0193 (3)	0.0278 (4)	0.0277 (4)	0.0008 (3)	0.0001 (3)	0.0045 (3)
C23	0.039 (2)	0.100 (5)	0.120 (6)	−0.009 (3)	0.026 (3)	−0.029 (4)
C24	0.081 (4)	0.057 (3)	0.095 (5)	−0.023 (3)	0.038 (4)	−0.016 (3)
C25	0.072 (3)	0.054 (3)	0.060 (3)	0.009 (2)	0.032 (3)	0.015 (2)
C26	0.049 (3)	0.060 (3)	0.050 (4)	0.013 (3)	0.021 (3)	0.014 (3)
C27	0.057 (3)	0.070 (3)	0.053 (3)	0.004 (2)	0.015 (2)	−0.018 (2)
O5'	0.0403 (14)	0.0526 (16)	0.0476 (15)	0.0081 (12)	0.0122 (12)	−0.0033 (12)
C23'	0.042 (2)	0.064 (3)	0.050 (2)	−0.0106 (18)	0.0138 (17)	−0.0147 (19)
C24'	0.059 (3)	0.047 (2)	0.075 (3)	0.008 (2)	0.037 (3)	0.001 (2)
C25'	0.071 (3)	0.051 (3)	0.072 (4)	0.003 (2)	0.036 (3)	0.001 (3)
C26'	0.083 (6)	0.053 (3)	0.056 (4)	0.006 (4)	0.026 (4)	0.009 (3)