Metal–organic framework-based photoelectrochemical detection sensors for tracing environmental pollutants^a.

Working electrode	Analyte	LOD	Linear concentration range	Ref.
Eu-MOF	Fe3+	0.0899 μM	1 μM∼100 mM	104
Cu-MOF-NH2	Kanamycin	0.1 nM	0.5 nM∼650 nM	105
NiPc-Ni MOF	Curcumin	0.8 nM	2.5 nM∼16 μM	106
Cu-BTC/g-C3N4	Glyphosate	0.13 pM	1 pM∼10 nM	100
Cu-BTC@Cu2O	Dioctyl phthalate	9.15 pM	25.0 pM∼0.1 μM	107
PCN-224/rGO	p-arsanilic acid	5.47 ng L−1	10 ng L−1∼10 mg L−1	108
CdS QDs/PCN-224	Doxorubicin hydrochloride	3.57 nM	10 nM∼1 μM	102
	Gentamicin sulfate	0.158 nM	1 nM∼1 μM
PCN-222@g-C3N4	Kanamycin sulfate	0.127 nM	1 nM∼100 nM	101
Ce-Por-MOFs/AgNWs	Ronidazole	0.038 nM	0.1 nM∼104 nM	109
ZIF-8@ZnIn2S4	Tetracycline	0.1 pM	1 pM∼700 pM	95
MIP@NH2-MIL-125(Ti)/TiO2	Oxytetracycline	60 pM	0.1 nM∼10 μM	97
CdS/Eu-MOF	Ampicillin	0.093 nM	0.1 nM∼0.2 μM	110
[Ru(bpy)3]2+@Ce-UiO-66/Mn:Bi2S3	Ofloxacin	6 pM	0.01 nM∼100 nM	98
g-C3N4/Au/NH2-UiO-66	d-penicillamine	0.0046 μM	10 nM∼400 μM	99
Er-MOF@AuNPs	Aflatoxin B1	19.6 fg mL−1	0.005 ng mL−1 ∼ 10.0 ng mL−1	111

^aEu-MOF: europium(iii)-based metal organic framework; Cu-MOF-NH₂: copper(ii) 2-aminoterephthalic acid; NiPc-Ni MOF: nickel phthalocyanine-based metal organic framework; Cu-BTC: copper(ii) benzene-1,3,5-tricarboxylate; Ce-Por-MOFs: Ce-porphyrin-metal–organic frameworks; NH₂-MIL-125(Ti): amino-functionalized titanium(iv) based MOFs; ZIF-8: zeolitic imidazolate framework-8; CdS QDs: CdS quantum dots; PCN-222, PCN-224: zirconium-porphyrin metal–organic framework; Ce-UiO-66: Ce doped zirconium-based MOF with terephthalic acid ligands; NH₂-UiO-66: zirconium-based MOF with 2-aminoterephthalic acid ligands; Er-MOF: erbium(iii)-based metal organic framework.